Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity
Alexey N. Bilyachenko
1, 2
,
Mikhail M Levitsky
1
,
Alexey I Yalymov
1
,
Alexander A. Korlyukov
1, 3
,
Viktor N Khrustalev
1, 2
,
Anna V. Vologzhanina
1
,
Lidia S Shulpina
1
,
Nikolay S Ikonnikov
1
,
Xavier Bantreil
5
,
Frédéric Lamaty
5
,
Jérôme Long
6
,
Joulia Larionova
6
,
Igor E Golub
1
,
Elena S Shubina
1
,
Georgiy B Shulpin
7, 8
Publication type: Journal Article
Publication date: 2016-11-07
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
27897426
General Chemistry
Catalysis
Abstract
A series of four unprecedented heterometallic metallagermsesquioxanes were synthesized. Their cage-like architectures have a unique type of molecular topology consisting of the hexairon oxo {Fe6 O19 } core surrounded in a triangular manner by three cyclic germoxanolates [PhGe(O)O]5 . This structural organization induces antiferromagnetic interactions between the FeIII ions through the oxygen atoms. Evaluated for this first time in catalysis, these compounds showed a high catalytic activity in the oxidation of alkanes and the oxidative formation of benzamides from alcohols.
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37
Total citations:
37
Citations from 2024:
4
(10%)
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GOST
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Bilyachenko A. N. et al. Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 49. pp. 15360-15363.
GOST all authors (up to 50)
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Bilyachenko A. N., Levitsky M. M., Yalymov A. I., Korlyukov A. A., Khrustalev V. N., Vologzhanina A. V., Shulpina L. S., Ikonnikov N. S., Trigub A. E., Dorovatovskii P. V., Bantreil X., Lamaty F., Long J., Larionova J., Golub I. E., Shubina E. S., Shulpin G. B. Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 49. pp. 15360-15363.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201607189
UR - https://doi.org/10.1002/anie.201607189
TI - Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity
T2 - Angewandte Chemie - International Edition
AU - Bilyachenko, Alexey N.
AU - Levitsky, Mikhail M
AU - Yalymov, Alexey I
AU - Korlyukov, Alexander A.
AU - Khrustalev, Viktor N
AU - Vologzhanina, Anna V.
AU - Shulpina, Lidia S
AU - Ikonnikov, Nikolay S
AU - Trigub, Alexander E
AU - Dorovatovskii, Pavel V.
AU - Bantreil, Xavier
AU - Lamaty, Frédéric
AU - Long, Jérôme
AU - Larionova, Joulia
AU - Golub, Igor E
AU - Shubina, Elena S
AU - Shulpin, Georgiy B
PY - 2016
DA - 2016/11/07
PB - Wiley
SP - 15360-15363
IS - 49
VL - 55
PMID - 27897426
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (up to 50 authors)
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@article{2016_Bilyachenko,
author = {Alexey N. Bilyachenko and Mikhail M Levitsky and Alexey I Yalymov and Alexander A. Korlyukov and Viktor N Khrustalev and Anna V. Vologzhanina and Lidia S Shulpina and Nikolay S Ikonnikov and Alexander E Trigub and Pavel V. Dorovatovskii and Xavier Bantreil and Frédéric Lamaty and Jérôme Long and Joulia Larionova and Igor E Golub and Elena S Shubina and Georgiy B Shulpin},
title = {Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity},
journal = {Angewandte Chemie - International Edition},
year = {2016},
volume = {55},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/anie.201607189},
number = {49},
pages = {15360--15363},
doi = {10.1002/anie.201607189}
}
Cite this
MLA
Copy
Bilyachenko, Alexey N., et al. “Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity.” Angewandte Chemie - International Edition, vol. 55, no. 49, Nov. 2016, pp. 15360-15363. https://doi.org/10.1002/anie.201607189.