On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet
Publication type: Journal Article
Publication date: 2016-11-22
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
27874236
General Chemistry
Catalysis
Abstract
We report a monometallic dysprosium complex, [Dy(Ot Bu)2 (py)5 ][BPh4 ] (5), that shows the largest effective energy barrier to magnetic relaxation of Ueff =1815(1) K. The massive magnetic anisotropy is due to bis-trans-disposed tert-butoxide ligands with weak equatorial pyridine donors, approaching proposed schemes for high-temperature single-molecule magnets (SMMs). The blocking temperature, TB , is 14 K, defined by zero-field-cooled magnetization experiments, and is the largest for any monometallic complex and equal with the current record for [Tb2 N2 {N(SiMe3 )2 }4 (THF)2 ].
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873
Total citations:
873
Citations from 2025:
70
(8.02%)
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Ding Y. S. et al. On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 52. pp. 16071-16074.
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Ding Y. S., Chilton N. F., Winpenny R. E. P., Zheng Y. On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 52. pp. 16071-16074.
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TY - JOUR
DO - 10.1002/anie.201609685
UR - https://doi.org/10.1002/anie.201609685
TI - On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet
T2 - Angewandte Chemie - International Edition
AU - Ding, You Song
AU - Chilton, Nicholas F.
AU - Winpenny, Richard E. P.
AU - Zheng, Yanzhen
PY - 2016
DA - 2016/11/22
PB - Wiley
SP - 16071-16074
IS - 52
VL - 55
PMID - 27874236
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Ding,
author = {You Song Ding and Nicholas F. Chilton and Richard E. P. Winpenny and Yanzhen Zheng},
title = {On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet},
journal = {Angewandte Chemie - International Edition},
year = {2016},
volume = {55},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/anie.201609685},
number = {52},
pages = {16071--16074},
doi = {10.1002/anie.201609685}
}
Cite this
MLA
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Ding, You Song, et al. “On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet.” Angewandte Chemie - International Edition, vol. 55, no. 52, Nov. 2016, pp. 16071-16074. https://doi.org/10.1002/anie.201609685.