Angewandte Chemie - International Edition, volume 57, issue 29, pages 9048-9053
High-Pressure Synthesis of a Nitrogen-Rich Inclusion Compound ReN8 ⋅x N2 with Conjugated Polymeric Nitrogen Chains
Maxim Bykov
1
,
E. Bykova
2
,
Egor Koemets
1
,
Timofey Fedotenko
1
,
Georgios Aprilis
3
,
K. Glazyrin
2
,
H.-P. Liermann
2
,
A.V. Ponomareva
4
,
Johan Tidholm
5
,
F. Tasnádi
5
,
I. A. Abrikosov
5
,
Publication type: Journal Article
Publication date: 2018-06-19
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
A nitrogen-rich compound, ReN8 ⋅x N2 , was synthesized by a direct reaction between rhenium and nitrogen at high pressure and high temperature in a laser-heated diamond anvil cell. Single-crystal X-ray diffraction revealed that the crystal structure, which is based on the ReN8 framework, has rectangular-shaped channels that accommodate nitrogen molecules. Thus, despite a very high synthesis pressure, exceeding 100 GPa, ReN8 ⋅x N2 is an inclusion compound. The amount of trapped nitrogen (x) depends on the synthesis conditions. The polydiazenediyl chains [-N=N-]∞ that constitute the framework have not been previously observed in any compound. Ab initio calculations on ReN8 ⋅x N2 provide strong support for the experimental results and conclusions.
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Bykov M. et al. High-Pressure Synthesis of a Nitrogen-Rich Inclusion Compound ReN8 ⋅x N2 with Conjugated Polymeric Nitrogen Chains // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 29. pp. 9048-9053.
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Bykov M., Bykova E., Koemets E., Fedotenko T., Aprilis G., Glazyrin K., Liermann H., Ponomareva A., Tidholm J., Tasnádi F., Abrikosov I. A., Dubrovinskaia N., Dubrovinsky L. High-Pressure Synthesis of a Nitrogen-Rich Inclusion Compound ReN8 ⋅x N2 with Conjugated Polymeric Nitrogen Chains // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 29. pp. 9048-9053.
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TY - JOUR
DO - 10.1002/anie.201805152
UR - https://doi.org/10.1002/anie.201805152
TI - High-Pressure Synthesis of a Nitrogen-Rich Inclusion Compound ReN8 ⋅x N2 with Conjugated Polymeric Nitrogen Chains
T2 - Angewandte Chemie - International Edition
AU - Koemets, Egor
AU - Bykov, Maxim
AU - Bykova, E.
AU - Fedotenko, Timofey
AU - Aprilis, Georgios
AU - Glazyrin, K.
AU - Liermann, H.-P.
AU - Ponomareva, A.V.
AU - Tidholm, Johan
AU - Tasnádi, F.
AU - Abrikosov, I. A.
AU - Dubrovinskaia, N.A.
AU - Dubrovinsky, L.
PY - 2018
DA - 2018/06/19 00:00:00
PB - Wiley
SP - 9048-9053
IS - 29
VL - 57
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2018_Bykov,
author = {Egor Koemets and Maxim Bykov and E. Bykova and Timofey Fedotenko and Georgios Aprilis and K. Glazyrin and H.-P. Liermann and A.V. Ponomareva and Johan Tidholm and F. Tasnádi and I. A. Abrikosov and N.A. Dubrovinskaia and L. Dubrovinsky},
title = {High-Pressure Synthesis of a Nitrogen-Rich Inclusion Compound ReN8 ⋅x N2 with Conjugated Polymeric Nitrogen Chains},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/anie.201805152},
number = {29},
pages = {9048--9053},
doi = {10.1002/anie.201805152}
}
Cite this
MLA
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Bykov, Maxim, et al. “High-Pressure Synthesis of a Nitrogen-Rich Inclusion Compound ReN8 ⋅x N2 with Conjugated Polymeric Nitrogen Chains.” Angewandte Chemie - International Edition, vol. 57, no. 29, Jun. 2018, pp. 9048-9053. https://doi.org/10.1002/anie.201805152.