Upconversion of Reductants
Publication type: Journal Article
Publication date: 2019-02-20
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
30063285
General Chemistry
Catalysis
Abstract
The many applications of photon upconversion-conversion of low-energy photons into high-energy photons-raises the question of the possibility of "electron upconversion". In this Review, we illustrate how the reduction potential can be increased by using the free energy of exergonic chemical reactions. Electron (reductant) upconversion can produce up to 20-25 kcal mol-1 of additional redox potential, thus creating powerful reductants under mild conditions. We will present the two common types of electron-upconverting systems-dissociative (based on unimolecular fragmentations) and associative (based on the bimolecular formation of three-electron bonds). The possible utility of reductant upconversion encompasses redox chain reactions in electrocatalytic processes, photoredox cascades, design of peroxide-based medicines, firefly luminescence, and reductive repair of DNA photodamage.
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Metrics
76
Total citations:
76
Citations from 2025:
7
(9.21%)
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GOST
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Syroeshkin M. et al. Upconversion of Reductants // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 17. pp. 5532-5550.
GOST all authors (up to 50)
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Syroeshkin M., Sykora J. L., Saverina E. A., Timofeeva V. A., Egorov M. P., Alabugin I. V. Upconversion of Reductants // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 17. pp. 5532-5550.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201807247
UR - https://doi.org/10.1002/anie.201807247
TI - Upconversion of Reductants
T2 - Angewandte Chemie - International Edition
AU - Syroeshkin, Mikhail
AU - Sykora, J. L.
AU - Saverina, Evgeniya A
AU - Timofeeva, Vladislava A
AU - Egorov, Mikhail P.
AU - Alabugin, Igor V.
PY - 2019
DA - 2019/02/20
PB - Wiley
SP - 5532-5550
IS - 17
VL - 58
PMID - 30063285
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Syroeshkin,
author = {Mikhail Syroeshkin and J. L. Sykora and Evgeniya A Saverina and Vladislava A Timofeeva and Mikhail P. Egorov and Igor V. Alabugin},
title = {Upconversion of Reductants},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.201807247},
number = {17},
pages = {5532--5550},
doi = {10.1002/anie.201807247}
}
Cite this
MLA
Copy
Syroeshkin, Mikhail, et al. “Upconversion of Reductants.” Angewandte Chemie - International Edition, vol. 58, no. 17, Feb. 2019, pp. 5532-5550. https://doi.org/10.1002/anie.201807247.