Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode.
Ruqaya Buhaibeh
1
,
Oleg A. Filippov
2
,
Antoine Bruneau Voisine
1, 3
,
Jérémy Willot
1
,
Carine Duhayon
1
,
D. A. Valyaev
1
,
Noël Lugan
1
,
Yves Canac
1
,
Publication type: Journal Article
Publication date: 2019-05-13
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
30860308
General Chemistry
Catalysis
Abstract
Deprotonation of the MnI NHC-phosphine complex fac-[MnBr(CO)3 (κ2 P,C-Ph2 PCH2 NHC)] (2) under a H2 atmosphere readily gives the hydride fac-[MnH(CO)3 (κ2 P,C-Ph2 PCH2 NHC)] (3) via the intermediacy of the highly reactive 18-e NHC-phosphinomethanide complex fac-[Mn(CO)3 (κ3 P,C,C-Ph2 PCHNHC)] (6 a). DFT calculations revealed that the preferred reaction mechanism involves the unsaturated 16-e mangana-substituted phosphonium ylide complex fac-[Mn(CO)3 (κ2 P,C-Ph2 P=CHNHC)] (6 b) as key intermediate able to activate H2 via a non-classical mode of metal-ligand cooperation implying a formal λ5 -P-λ3 -P phosphorus valence change. Complex 2 is shown to be one of the most efficient pre-catalysts for ketone hydrogenation in the MnI series reported to date (TON up to 6200).
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Total citations:
88
Citations from 2024:
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(25%)
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GOST
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Buhaibeh R. et al. Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode. // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 20. pp. 6727-6731.
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Buhaibeh R., Filippov O. A., Bruneau Voisine A., Willot J., Duhayon C., Valyaev D. A., Lugan N., Canac Y., Sortais J. Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode. // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 20. pp. 6727-6731.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201901169
UR - https://doi.org/10.1002/anie.201901169
TI - Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode.
T2 - Angewandte Chemie - International Edition
AU - Buhaibeh, Ruqaya
AU - Filippov, Oleg A.
AU - Bruneau Voisine, Antoine
AU - Willot, Jérémy
AU - Duhayon, Carine
AU - Valyaev, D. A.
AU - Lugan, Noël
AU - Canac, Yves
AU - Sortais, Jean-Baptiste
PY - 2019
DA - 2019/05/13
PB - Wiley
SP - 6727-6731
IS - 20
VL - 58
PMID - 30860308
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Buhaibeh,
author = {Ruqaya Buhaibeh and Oleg A. Filippov and Antoine Bruneau Voisine and Jérémy Willot and Carine Duhayon and D. A. Valyaev and Noël Lugan and Yves Canac and Jean-Baptiste Sortais},
title = {Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode.},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/anie.201901169},
number = {20},
pages = {6727--6731},
doi = {10.1002/anie.201901169}
}
Cite this
MLA
Copy
Buhaibeh, Ruqaya, et al. “Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode..” Angewandte Chemie - International Edition, vol. 58, no. 20, May. 2019, pp. 6727-6731. https://doi.org/10.1002/anie.201901169.