Angewandte Chemie - International Edition, volume 59, issue 26, pages 10321-10326
High‐Pressure Synthesis of Metal–Inorganic Frameworks Hf 4 N 20 ⋅N 2 , WN 8 ⋅N 2 , and Os 5 N 28 ⋅3 N 2 with Polymeric Nitrogen Linkers
Maxim Bykov
1, 2, 3
,
Stella Chariton
4
,
E. Bykova
3
,
Saiana Khandarkhaeva
2
,
Timofey Fedotenko
5
,
A.V. Ponomareva
6
,
Johan Tidholm
7
,
F. Tasnádi
7
,
I. A. Abrikosov
7
,
Pavel Sedmak
8
,
V. Prakapenka
4
,
M. Hanfland
8
,
H.-P. Liermann
9
,
MOHAMMAD MAHMOOD
1
,
N.A. Dubrovinskaia
5, 7
,
3
The Earth and Planets Laboratory Carnegie Institution for Science 5241 Broad Branch Road, NW Washington DC 20015 USA
|
Publication type: Journal Article
Publication date: 2020-05-08
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
PubMed ID:
32212190
General Chemistry
Catalysis
Abstract
Polynitrides are intrinsically thermodynamically unstable at ambient conditions and require peculiar synthetic approaches. Now, a one-step synthesis of metal-inorganic frameworks Hf4 N20 ⋅N2 , WN8 ⋅N2 , and Os5 N28 ⋅3 N2 via direct reactions between elements in a diamond anvil cell at pressures exceeding 100 GPa is reported. The porous frameworks (Hf4 N20 , WN8 , and Os5 N28 ) are built from transition-metal atoms linked either by polymeric polydiazenediyl (polyacetylene-like) nitrogen chains or through dinitrogen units. Triply bound dinitrogen molecules occupy channels of these frameworks. Owing to conjugated polydiazenediyl chains, these compounds exhibit metallic properties. The high-pressure reaction between Hf and N2 also leads to a non-centrosymmetric polynitride Hf2 N11 that features double-helix catena-poly[tetraz-1-ene-1,4-diyl] nitrogen chains [-N-N-N=N-]∞ .
Top-30
Citations by journals
|
1
2
3
4
5
|
|
|
Inorganic Chemistry
5 publications, 12.2%
|
|
|
Nature Chemistry
2 publications, 4.88%
|
|
|
Physical Review Letters
2 publications, 4.88%
|
|
|
Journal of the American Chemical Society
2 publications, 4.88%
|
|
|
Physical Review B
2 publications, 4.88%
|
|
|
Chinese Physics Letters
2 publications, 4.88%
|
|
|
Angewandte Chemie
2 publications, 4.88%
|
|
|
Angewandte Chemie - International Edition
2 publications, 4.88%
|
|
|
Dalton Transactions
2 publications, 4.88%
|
|
|
Matter and Radiation at Extremes
1 publication, 2.44%
|
|
|
Journal of Applied Crystallography
1 publication, 2.44%
|
|
|
Nature
1 publication, 2.44%
|
|
|
Science China: Physics, Mechanics and Astronomy
1 publication, 2.44%
|
|
|
Journal of Physical Chemistry B
1 publication, 2.44%
|
|
|
Physica Status Solidi (B): Basic Research
1 publication, 2.44%
|
|
|
Journal of Physical Chemistry C
1 publication, 2.44%
|
|
|
JACS Au
1 publication, 2.44%
|
|
|
Nanoscale
1 publication, 2.44%
|
|
|
Ceramics International
1 publication, 2.44%
|
|
|
Science Bulletin
1 publication, 2.44%
|
|
|
Physical Review Materials
1 publication, 2.44%
|
|
|
Nature Communications
1 publication, 2.44%
|
|
|
Journal of Physical Chemistry Letters
1 publication, 2.44%
|
|
|
Microstructures
1 publication, 2.44%
|
|
|
Advanced Functional Materials
1 publication, 2.44%
|
|
|
Physical Chemistry Chemical Physics
1 publication, 2.44%
|
|
|
Russian Chemical Reviews
1 publication, 2.44%
|
|
|
1
2
3
4
5
|
Citations by publishers
|
2
4
6
8
10
12
|
|
|
American Chemical Society (ACS)
11 publications, 26.83%
|
|
|
Wiley
6 publications, 14.63%
|
|
|
American Physical Society (APS)
5 publications, 12.2%
|
|
|
Springer Nature
4 publications, 9.76%
|
|
|
Royal Society of Chemistry (RSC)
4 publications, 9.76%
|
|
|
Elsevier
3 publications, 7.32%
|
|
|
IOP Publishing
2 publications, 4.88%
|
|
|
American Institute of Physics (AIP)
1 publication, 2.44%
|
|
|
International Union of Crystallography (IUCr)
1 publication, 2.44%
|
|
|
Science in China Press
1 publication, 2.44%
|
|
|
OAE Publishing Inc.
1 publication, 2.44%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.44%
|
|
|
2
4
6
8
10
12
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2020,2021,2022,2023,2024],"ids":[0,0,0,0,0],"codes":[0,0,0,0,0],"imageUrls":["","","","",""],"datasets":[{"label":"Citations number","data":[2,9,12,9,9],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["4.88","21.95","29.27","21.95","21.95"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Inorganic Chemistry","Nature Chemistry","Physical Review Letters","Journal of the American Chemical Society","Physical Review B","Chinese Physics Letters","Angewandte Chemie","Angewandte Chemie - International Edition","Dalton Transactions","Matter and Radiation at Extremes","Journal of Applied Crystallography","Nature","Science China: Physics, Mechanics and Astronomy","Journal of Physical Chemistry B","Physica Status Solidi (B): Basic Research","Journal of Physical Chemistry C","JACS Au","Nanoscale","Ceramics International","Science Bulletin","Physical Review Materials","Nature Communications","Journal of Physical Chemistry Letters","Microstructures","Advanced Functional Materials","Physical Chemistry Chemical Physics","Russian Chemical Reviews"],"ids":[24714,17228,4343,4813,25280,22690,25450,19215,8473,23140,11574,14611,3599,14990,11584,8859,26622,228,15103,17978,7673,3231,21963,30938,7715,1773,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/xG3oC19920mmFVqkoVEGKGaMCeoalzyvWxPkVox5_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/0oGA3odz6rRHYyWD8vQnHiPJ8KIaP1PtNoJm7RE1_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[5,2,2,2,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[12.2,4.88,4.88,4.88,4.88,4.88,4.88,4.88,4.88,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44,2.44],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Wiley","American Physical Society (APS)","Springer Nature","Royal Society of Chemistry (RSC)","Elsevier","IOP Publishing","American Institute of Physics (AIP)","International Union of Crystallography (IUCr)","Science in China Press","OAE Publishing Inc.","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,11,1539,8,123,17,2075,250,730,6481,7181,9422],"codes":[0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/xG3oC19920mmFVqkoVEGKGaMCeoalzyvWxPkVox5_medium.webp","","\/storage\/images\/resized\/0oGA3odz6rRHYyWD8vQnHiPJ8KIaP1PtNoJm7RE1_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[11,6,5,4,4,3,2,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[26.83,14.63,12.2,9.76,9.76,7.32,4.88,2.44,2.44,2.44,2.44,2.44],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0],"percentage":["0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,0,0,0],"percentage":["0","2.44","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,0,0,0],"percentage":["0","0","0","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,8,12,7,7],"percentage":["4.88","19.51","29.27","17.07","17.07"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,2,2],"percentage":["0","0","0","4.88","4.88"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,1,0,0,0],"percentage":["0","2.44","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,1,1,0],"percentage":["0","0","2.44","2.44","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,1,2,0,2],"percentage":["2.44","2.44","4.88","0","4.88"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,6,8,6,5],"percentage":["2.44","14.63","19.51","14.63","12.2"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,1,1,2,2],"percentage":["0","2.44","2.44","4.88","4.88"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Bykov M. et al. High‐Pressure Synthesis of Metal–Inorganic Frameworks Hf 4 N 20 ⋅N 2 , WN 8 ⋅N 2 , and Os 5 N 28 ⋅3 N 2 with Polymeric Nitrogen Linkers // Angewandte Chemie - International Edition. 2020. Vol. 59. No. 26. pp. 10321-10326.
GOST all authors (up to 50)
Copy
Bykov M., Chariton S., Bykova E., Khandarkhaeva S., Fedotenko T., Ponomareva A., Tidholm J., Tasnádi F., Abrikosov I. A., Sedmak P., Prakapenka V., Hanfland M., Liermann H., MAHMOOD M., Goncharov A., Dubrovinskaia N., Dubrovinsky L. High‐Pressure Synthesis of Metal–Inorganic Frameworks Hf 4 N 20 ⋅N 2 , WN 8 ⋅N 2 , and Os 5 N 28 ⋅3 N 2 with Polymeric Nitrogen Linkers // Angewandte Chemie - International Edition. 2020. Vol. 59. No. 26. pp. 10321-10326.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.202002487
UR - https://doi.org/10.1002/anie.202002487
TI - High‐Pressure Synthesis of Metal–Inorganic Frameworks Hf 4 N 20 ⋅N 2 , WN 8 ⋅N 2 , and Os 5 N 28 ⋅3 N 2 with Polymeric Nitrogen Linkers
T2 - Angewandte Chemie - International Edition
AU - Sedmak, Pavel
AU - MAHMOOD, MOHAMMAD
AU - Bykov, Maxim
AU - Hanfland, M.
AU - Dubrovinskaia, N.A.
AU - Dubrovinsky, L.
AU - Chariton, Stella
AU - Bykova, E.
AU - Khandarkhaeva, Saiana
AU - Fedotenko, Timofey
AU - Ponomareva, A.V.
AU - Tidholm, Johan
AU - Tasnádi, F.
AU - Abrikosov, I. A.
AU - Prakapenka, V.
AU - Liermann, H.-P.
AU - Goncharov, Alexander
PY - 2020
DA - 2020/05/08 00:00:00
PB - Wiley
SP - 10321-10326
IS - 26
VL - 59
PMID - 32212190
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex
Copy
@article{2020_Bykov,
author = {Pavel Sedmak and MOHAMMAD MAHMOOD and Maxim Bykov and M. Hanfland and N.A. Dubrovinskaia and L. Dubrovinsky and Stella Chariton and E. Bykova and Saiana Khandarkhaeva and Timofey Fedotenko and A.V. Ponomareva and Johan Tidholm and F. Tasnádi and I. A. Abrikosov and V. Prakapenka and H.-P. Liermann and Alexander Goncharov},
title = {High‐Pressure Synthesis of Metal–Inorganic Frameworks Hf 4 N 20 ⋅N 2 , WN 8 ⋅N 2 , and Os 5 N 28 ⋅3 N 2 with Polymeric Nitrogen Linkers},
journal = {Angewandte Chemie - International Edition},
year = {2020},
volume = {59},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/anie.202002487},
number = {26},
pages = {10321--10326},
doi = {10.1002/anie.202002487}
}
Cite this
MLA
Copy
Bykov, Maxim, et al. “High‐Pressure Synthesis of Metal–Inorganic Frameworks Hf 4 N 20 ⋅N 2 , WN 8 ⋅N 2 , and Os 5 N 28 ⋅3 N 2 with Polymeric Nitrogen Linkers.” Angewandte Chemie - International Edition, vol. 59, no. 26, May. 2020, pp. 10321-10326. https://doi.org/10.1002/anie.202002487.