Alkyne insertion into the M-P and M-H bonds (M=Pd, Ni, Pt, and Rh): A theoretical mechanistic study of the C-P and C-H bond-formation steps
Publication type: Journal Article
Publication date: 2011-04-07
scimago Q2
wos Q2
SJR: 0.751
CiteScore: 5.9
Impact factor: 3.3
ISSN: 18614728, 1861471X
PubMed ID:
21480533
General Chemistry
Organic Chemistry
Biochemistry
Abstract
In hydrogen-metal-phosphorus (H-M-P) transition metal complexes (proposed as intermediates of H-P bond addition to alkynes in the catalytic hydrophosphorylation, hydrophosphinylation, and hydrophospination reactions), alkyne insertion into the metal-hydrogen bond was found much more facile compared to alkyne insertion into the metal-phosphorus bond. The conclusion was verified for different metals (Pd, Ni, Pt, and Rh), ligands, and phosphorus groups at various theory levels (B3LYP, B3PW91, BLYP, MP2, and ONIOM). The relative reactivity of the metal complexes in the reaction with alkynes was estimated and decreased in the order of Ni>Pd>Rh>Pt. A trend in relative reactivity was established for various types of phosphorus groups: PR(2)>P(O)R(2)>P(O)(OR)(2), which showed a decrease in rate upon increasing the number of the oxygen atoms attached to the phosphorus center.
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Total citations:
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Citations from 2025:
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Ananikov V. P., Beletskaya I. P. Alkyne insertion into the M-P and M-H bonds (M=Pd, Ni, Pt, and Rh): A theoretical mechanistic study of the C-P and C-H bond-formation steps // Chemistry - An Asian Journal. 2011. Vol. 6. No. 6. pp. 1423-1430.
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Ananikov V. P., Beletskaya I. P. Alkyne insertion into the M-P and M-H bonds (M=Pd, Ni, Pt, and Rh): A theoretical mechanistic study of the C-P and C-H bond-formation steps // Chemistry - An Asian Journal. 2011. Vol. 6. No. 6. pp. 1423-1430.
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TY - JOUR
DO - 10.1002/asia.201000840
UR - https://doi.org/10.1002/asia.201000840
TI - Alkyne insertion into the M-P and M-H bonds (M=Pd, Ni, Pt, and Rh): A theoretical mechanistic study of the C-P and C-H bond-formation steps
T2 - Chemistry - An Asian Journal
AU - Ananikov, Valentine P.
AU - Beletskaya, Irina P.
PY - 2011
DA - 2011/04/07
PB - Wiley
SP - 1423-1430
IS - 6
VL - 6
PMID - 21480533
SN - 1861-4728
SN - 1861-471X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Ananikov,
author = {Valentine P. Ananikov and Irina P. Beletskaya},
title = {Alkyne insertion into the M-P and M-H bonds (M=Pd, Ni, Pt, and Rh): A theoretical mechanistic study of the C-P and C-H bond-formation steps},
journal = {Chemistry - An Asian Journal},
year = {2011},
volume = {6},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/asia.201000840},
number = {6},
pages = {1423--1430},
doi = {10.1002/asia.201000840}
}
Cite this
MLA
Copy
Ananikov, Valentine P., and Irina P. Beletskaya. “Alkyne insertion into the M-P and M-H bonds (M=Pd, Ni, Pt, and Rh): A theoretical mechanistic study of the C-P and C-H bond-formation steps.” Chemistry - An Asian Journal, vol. 6, no. 6, Apr. 2011, pp. 1423-1430. https://doi.org/10.1002/asia.201000840.
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