Synthesis of Functionalized (η5‐Indenyl)rhodium(III) Complexes and Their Application to C−H Bond Functionalization
Publication type: Journal Article
Publication date: 2018-02-01
scimago Q2
wos Q2
SJR: 0.751
CiteScore: 5.9
Impact factor: 3.3
ISSN: 18614728, 1861471X
PubMed ID:
29336528
General Chemistry
Organic Chemistry
Biochemistry
Abstract
It has been established that reductive complexation of functionalized benzofulvenes, which are readily prepared from commercially available indene and 2‐methylindene, with RhCl3 in ethanol affords the corresponding indenyl–rhodium(III) dichlorides bearing substituents at the 1‐ (H or CO2Et), 2‐ (H or Me), and 3‐ [CH2Ph or CH2(2‐MeOC6H4)] positions. The indenyl–rhodium(III) complexes bearing one ethoxycarbonyl group showed higher thermal stability and regioselectivity than our previously reported CpERhIII complex toward the oxidative [3+2] annulation of acetanilides with internal alkynes.
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32
Total citations:
32
Citations from 2025:
3
(9.38%)
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GOST
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Terasawa J. et al. Synthesis of Functionalized (η5‐Indenyl)rhodium(III) Complexes and Their Application to C−H Bond Functionalization // Chemistry - An Asian Journal. 2018. Vol. 13. No. 5. pp. 505-509.
GOST all authors (up to 50)
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Terasawa J., Shibata Yu., Kimura Y., Tanaka K. Synthesis of Functionalized (η5‐Indenyl)rhodium(III) Complexes and Their Application to C−H Bond Functionalization // Chemistry - An Asian Journal. 2018. Vol. 13. No. 5. pp. 505-509.
Cite this
RIS
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TY - JOUR
DO - 10.1002/asia.201701716
UR - https://onlinelibrary.wiley.com/doi/10.1002/asia.201701716
TI - Synthesis of Functionalized (η5‐Indenyl)rhodium(III) Complexes and Their Application to C−H Bond Functionalization
T2 - Chemistry - An Asian Journal
AU - Terasawa, Jyunichi
AU - Shibata, Yu
AU - Kimura, Yuki
AU - Tanaka, Ken
PY - 2018
DA - 2018/02/01
PB - Wiley
SP - 505-509
IS - 5
VL - 13
PMID - 29336528
SN - 1861-4728
SN - 1861-471X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Terasawa,
author = {Jyunichi Terasawa and Yu Shibata and Yuki Kimura and Ken Tanaka},
title = {Synthesis of Functionalized (η5‐Indenyl)rhodium(III) Complexes and Their Application to C−H Bond Functionalization},
journal = {Chemistry - An Asian Journal},
year = {2018},
volume = {13},
publisher = {Wiley},
month = {feb},
url = {https://onlinelibrary.wiley.com/doi/10.1002/asia.201701716},
number = {5},
pages = {505--509},
doi = {10.1002/asia.201701716}
}
Cite this
MLA
Copy
Terasawa, Jyunichi, et al. “Synthesis of Functionalized (η5‐Indenyl)rhodium(III) Complexes and Their Application to C−H Bond Functionalization.” Chemistry - An Asian Journal, vol. 13, no. 5, Feb. 2018, pp. 505-509. https://onlinelibrary.wiley.com/doi/10.1002/asia.201701716.