Ionic Complexes of Tetra- and Nonanuclear Cage Copper(II) Phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
Alexey N Bilyachenko
1, 2
,
Alena N Kulakova
1, 2
,
Mikhail M Levitsky
1
,
Alexander A. Korlyukov
1, 3
,
Victor N. Khrustalev
2
,
Anna V. Vologzhanina
1
,
Aleksei A Titov
1, 2
,
Frédéric Lamaty
5
,
Xavier Bantreil
5
,
Benoît Villemejeanne
5
,
Cindy Ruiz
5
,
Jean Martinez
5
,
Elena S Shubina
1
,
Georgiy B Shulpin
6, 7
Publication type: Journal Article
Publication date: 2017-11-14
scimago Q1
wos Q2
SJR: 0.941
CiteScore: 6.1
Impact factor: 3.9
ISSN: 18673880, 18673899
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Herein, we describe an approach to cage metallasilsesquioxanes by self‐assembly with 1,2‐bis(diphenylphosphino)ethane as a key reactant. This approach allowed us to achieve a unique family of complexes that includes anionic tetra‐ and nonanuclear cage copper(II) sodium silsesquioxane and cationic copper(I) 1,2‐bis(diphenylphosphino)ethane components. Additional representatives of this intriguing metallasilsesquioxane family (Cu9Na6 and Cu9Na3Cs3) were obtained through the replacement of the original ethanol‐based reaction medium by DMSO. The fascinating structural peculiarities of all products were established by using XRD and topological studies. Initial tests for the application of the synthesized complexes as catalysts revealed their very high activity in the homogeneous oxidation of alkanes and alcohols to produce alkyl hydroperoxides, ketones, and amides.
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Total citations:
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Citations from 2024:
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(5%)
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Bilyachenko A. N. et al. Ionic Complexes of Tetra- and Nonanuclear Cage Copper(II) Phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis // ChemCatChem. 2017. Vol. 9. No. 23. pp. 4437-4447.
GOST all authors (up to 50)
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Bilyachenko A. N., Kulakova A. N., Levitsky M. M., Korlyukov A. A., Khrustalev V. N., Vologzhanina A. V., Titov A. A., Dorovatovskii P. V., Shul'pin G. B., Lamaty F., Bantreil X., Villemejeanne B., Ruiz C., Martinez J., Shubina E. S., Shulpin G. B. Ionic Complexes of Tetra- and Nonanuclear Cage Copper(II) Phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis // ChemCatChem. 2017. Vol. 9. No. 23. pp. 4437-4447.
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RIS
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TY - JOUR
DO - 10.1002/cctc.201701063
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201701063
TI - Ionic Complexes of Tetra- and Nonanuclear Cage Copper(II) Phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
T2 - ChemCatChem
AU - Bilyachenko, Alexey N
AU - Kulakova, Alena N
AU - Levitsky, Mikhail M
AU - Korlyukov, Alexander A.
AU - Khrustalev, Victor N.
AU - Vologzhanina, Anna V.
AU - Titov, Aleksei A
AU - Dorovatovskii, Pavel V.
AU - Shul'pin, Georgiy B.
AU - Lamaty, Frédéric
AU - Bantreil, Xavier
AU - Villemejeanne, Benoît
AU - Ruiz, Cindy
AU - Martinez, Jean
AU - Shubina, Elena S
AU - Shulpin, Georgiy B
PY - 2017
DA - 2017/11/14
PB - Wiley
SP - 4437-4447
IS - 23
VL - 9
SN - 1867-3880
SN - 1867-3899
ER -
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@article{2017_Bilyachenko,
author = {Alexey N Bilyachenko and Alena N Kulakova and Mikhail M Levitsky and Alexander A. Korlyukov and Victor N. Khrustalev and Anna V. Vologzhanina and Aleksei A Titov and Pavel V. Dorovatovskii and Georgiy B. Shul'pin and Frédéric Lamaty and Xavier Bantreil and Benoît Villemejeanne and Cindy Ruiz and Jean Martinez and Elena S Shubina and Georgiy B Shulpin},
title = {Ionic Complexes of Tetra- and Nonanuclear Cage Copper(II) Phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis},
journal = {ChemCatChem},
year = {2017},
volume = {9},
publisher = {Wiley},
month = {nov},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201701063},
number = {23},
pages = {4437--4447},
doi = {10.1002/cctc.201701063}
}
Cite this
MLA
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Bilyachenko, Alexey N., et al. “Ionic Complexes of Tetra- and Nonanuclear Cage Copper(II) Phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis.” ChemCatChem, vol. 9, no. 23, Nov. 2017, pp. 4437-4447. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201701063.