Ytterbocenes as One- and Two-Electron Reductants in their Reactions with Diazadienes: YbIII Mixed-Ligand Bent-Sandwich Complexes Containing a Dianion of Diazabutadiene
2
Laboratoire de Chimie Moleculaire et Organisation du Solide, Batiment 17, Case Courrier OO7, Place Eugene Bataillon, 34095 Montpellier Cedex 5, France
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Publication type: Journal Article
Publication date: 2007-06-04
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
17366494
General Chemistry
Catalysis
Organic Chemistry
Abstract
Ytterbocene [Yb(C(5)MeH(4))(2)(thf)(2)] reacts with diazabutadiene 2,6-iPr(2)C(6)H(3)-N=CH-CH=N-C(6)H(3)iPr(2)-2,6 (DAD) as a one-electron reductant to afford a bis(cyclopentadienyl) Yb(III) derivative containing a DAD radical anion [Yb(C(5)MeH(4))(2)(dad(-.))]. However, ytterbocenes [YbCp*(2)(thf)(2)] (Cp*=C(5)Me(5), C(5)Me(4)H) coordinated by sterically demanding cyclopentadienyl ligands act as two-electron reductants in their reactions with DAD. These reactions occur by abstraction of one Cp* ring and result in the formation of novel Yb(III) mixed-ligand bent-sandwich complexes, [YbCp*(dad)(thf)], in which the dianion of DAD has an uncommon terminal eta(4)-coordination to the ytterbium atom. The variable-temperature magnetic measurements of complex [Yb(C(5)Me(5))(dad)(thf)] suggest the existence of redox tautomerism for this compound.
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Trifonov A. A. et al. Ytterbocenes as One- and Two-Electron Reductants in their Reactions with Diazadienes: YbIII Mixed-Ligand Bent-Sandwich Complexes Containing a Dianion of Diazabutadiene // Chemistry - A European Journal. 2007. Vol. 13. No. 17. pp. 4981-4987.
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Trifonov A. A., Borovkov I. A., Fedorova E. A., Fukin G. K., Larionova J., Druzhkov N. O., Cherkasov V. K. Ytterbocenes as One- and Two-Electron Reductants in their Reactions with Diazadienes: YbIII Mixed-Ligand Bent-Sandwich Complexes Containing a Dianion of Diazabutadiene // Chemistry - A European Journal. 2007. Vol. 13. No. 17. pp. 4981-4987.
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TY - JOUR
DO - 10.1002/chem.200601481
UR - https://doi.org/10.1002/chem.200601481
TI - Ytterbocenes as One- and Two-Electron Reductants in their Reactions with Diazadienes: YbIII Mixed-Ligand Bent-Sandwich Complexes Containing a Dianion of Diazabutadiene
T2 - Chemistry - A European Journal
AU - Trifonov, Alexander A.
AU - Borovkov, Ivan A
AU - Fedorova, Elena A
AU - Fukin, Georgii K.
AU - Larionova, Joulia
AU - Druzhkov, Nikolai O
AU - Cherkasov, Vladimir Kuzmich
PY - 2007
DA - 2007/06/04
PB - Wiley
SP - 4981-4987
IS - 17
VL - 13
PMID - 17366494
SN - 0947-6539
SN - 1521-3765
ER -
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BibTex (up to 50 authors)
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@article{2007_Trifonov,
author = {Alexander A. Trifonov and Ivan A Borovkov and Elena A Fedorova and Georgii K. Fukin and Joulia Larionova and Nikolai O Druzhkov and Vladimir Kuzmich Cherkasov},
title = {Ytterbocenes as One- and Two-Electron Reductants in their Reactions with Diazadienes: YbIII Mixed-Ligand Bent-Sandwich Complexes Containing a Dianion of Diazabutadiene},
journal = {Chemistry - A European Journal},
year = {2007},
volume = {13},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/chem.200601481},
number = {17},
pages = {4981--4987},
doi = {10.1002/chem.200601481}
}
Cite this
MLA
Copy
Trifonov, Alexander A., et al. “Ytterbocenes as One- and Two-Electron Reductants in their Reactions with Diazadienes: YbIII Mixed-Ligand Bent-Sandwich Complexes Containing a Dianion of Diazabutadiene.” Chemistry - A European Journal, vol. 13, no. 17, Jun. 2007, pp. 4981-4987. https://doi.org/10.1002/chem.200601481.