Nitramines with Varying Sensitivities: Functionalized Dipyrazolyl-N-nitromethanamines as Energetic Materials
Publication type: Journal Article
Publication date: 2013-05-16
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
23681737
General Chemistry
Catalysis
Organic Chemistry
Abstract
1,3-Dichloro-2-nitro-2-azapropane is an excellent precursor to dense energetic functionalized dipyrazolyl-N-nitromethanamines. This new family of energetic compounds was fully characterized by using (1)H, (13)C, and (15)N NMR and IR spectroscopy, differential scanning calorimetry, elemental analysis, and impact sensitivity tests. Additionally, single-crystal X-ray structuring was done for 3 and 5·CH3CN, which gave insight into structural characteristics. The experimentally determined densities of 2-9 fall between 1.69 and 1.90 g cm(-3). Heats of formation and detonation properties were calculated by using Gaussian 03 and EXPLO5 programs, respectively. The influence of different energetic moieties on the structural and energetic properties was established theoretically.
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GOST
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Zhang J. et al. Nitramines with Varying Sensitivities: Functionalized Dipyrazolyl-N-nitromethanamines as Energetic Materials // Chemistry - A European Journal. 2013. Vol. 19. No. 27. pp. 8929-8936.
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Zhang J., He C., Parrish D. A., Shreeve J. M. Nitramines with Varying Sensitivities: Functionalized Dipyrazolyl-N-nitromethanamines as Energetic Materials // Chemistry - A European Journal. 2013. Vol. 19. No. 27. pp. 8929-8936.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201300747
UR - https://doi.org/10.1002/chem.201300747
TI - Nitramines with Varying Sensitivities: Functionalized Dipyrazolyl-N-nitromethanamines as Energetic Materials
T2 - Chemistry - A European Journal
AU - Zhang, Jiaheng
AU - He, Chunlin
AU - Parrish, Damon A.
AU - Shreeve, Jean'ne M.
PY - 2013
DA - 2013/05/16
PB - Wiley
SP - 8929-8936
IS - 27
VL - 19
PMID - 23681737
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Zhang,
author = {Jiaheng Zhang and Chunlin He and Damon A. Parrish and Jean'ne M. Shreeve},
title = {Nitramines with Varying Sensitivities: Functionalized Dipyrazolyl-N-nitromethanamines as Energetic Materials},
journal = {Chemistry - A European Journal},
year = {2013},
volume = {19},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/chem.201300747},
number = {27},
pages = {8929--8936},
doi = {10.1002/chem.201300747}
}
Cite this
MLA
Copy
Zhang, Jiaheng, et al. “Nitramines with Varying Sensitivities: Functionalized Dipyrazolyl-N-nitromethanamines as Energetic Materials.” Chemistry - A European Journal, vol. 19, no. 27, May. 2013, pp. 8929-8936. https://doi.org/10.1002/chem.201300747.