Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies
Publication type: Journal Article
Publication date: 2015-05-07
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
25950426
General Chemistry
Catalysis
Organic Chemistry
Abstract
The transmetalation of bimetallic copper-sodium silsesquioxane cages, namely, [(PhSiO1.5 )10 (CuO)2 (NaO0.5 )2 ] ("Cooling Tower"; 1), [(PhSiO1.5 )12 (CuO)4 (NaO0.5 )4 ] ("Globule"; 2), and [(PhSiO1.5 )6 (CuO)4 (NaO0.5 )4 (PhSiO1.5 )6 ] ("Sandwich"; 3), resulted in the generation of three types of hexanuclear cylinder-like copper silsesqui- oxanes, [(PhSiO1.5 )12 (CuO)6 (C4 H9 OH)2 (C2 H5 OH)6 ] (4), [(PhSiO1.5 )12 (CuO)6 (C4 H8 O2 )4 (PhCN)2 (MeOH)4 ] (5), and [(PhSiO1.5 )12 (CuO)6 (NaCl)(C4 H8 O2 )12 (H2 O)2 ] (6). The products show a prominent "solvating system-structure" dependency, as determined by X-ray diffraction. Topological analysis of cages 1-6 was also performed. In addition, DFT theory was used to examine the structures of the Cooling Tower and Cylinder compounds, as well as the spin density distributions. Compounds 1, 2, and 5 were applied as catalysts for the direct oxidation of alcohols and amines into the corresponding amides. Compound 6 is an excellent catalyst in the oxidation reactions of benzene and alcohols.
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72
Total citations:
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Citations from 2025:
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(6.95%)
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Bilyachenko A. N. et al. Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies // Chemistry - A European Journal. 2015. Vol. 21. No. 24. pp. 8758-8770.
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Bilyachenko A. N., Dronova M. S., Yalymov A. I., Lamaty F., Bantreil X., Martinez J., Bizet C., Shulpina L. S., Korlyukov A. A., Arkhipov D. E., Levitsky M. M., Shubina E. S., Kirillov A. M., Shulpin G. B. Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies // Chemistry - A European Journal. 2015. Vol. 21. No. 24. pp. 8758-8770.
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TY - JOUR
DO - 10.1002/chem.201500791
UR - https://doi.org/10.1002/chem.201500791
TI - Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies
T2 - Chemistry - A European Journal
AU - Bilyachenko, Alexey N.
AU - Dronova, Marina S
AU - Yalymov, Alexey I
AU - Lamaty, Frédéric
AU - Bantreil, Xavier
AU - Martinez, Jean
AU - Bizet, Christelle
AU - Shulpina, Lidia S
AU - Korlyukov, Alexander A.
AU - Arkhipov, Dmitry E.
AU - Levitsky, Mikhail M
AU - Shubina, Elena S
AU - Kirillov, Alexander M
AU - Shulpin, Georgiy B
PY - 2015
DA - 2015/05/07
PB - Wiley
SP - 8758-8770
IS - 24
VL - 21
PMID - 25950426
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
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@article{2015_Bilyachenko,
author = {Alexey N. Bilyachenko and Marina S Dronova and Alexey I Yalymov and Frédéric Lamaty and Xavier Bantreil and Jean Martinez and Christelle Bizet and Lidia S Shulpina and Alexander A. Korlyukov and Dmitry E. Arkhipov and Mikhail M Levitsky and Elena S Shubina and Alexander M Kirillov and Georgiy B Shulpin},
title = {Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies},
journal = {Chemistry - A European Journal},
year = {2015},
volume = {21},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/chem.201500791},
number = {24},
pages = {8758--8770},
doi = {10.1002/chem.201500791}
}
Cite this
MLA
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Bilyachenko, Alexey N., et al. “Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies.” Chemistry - A European Journal, vol. 21, no. 24, May. 2015, pp. 8758-8770. https://doi.org/10.1002/chem.201500791.