Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene
Oleg A. Filippov
1
,
Aleksei A Titov
1
,
Ekaterina A Guseva
1
,
Alexander F. Smol’yakov
1
,
Fedor Dolgushin
1
,
Lina M. epstein
1
,
Publication type: Journal Article
Publication date: 2015-07-27
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
26332228
General Chemistry
Catalysis
Organic Chemistry
Abstract
According to spectroscopic (NMR, IR, UV/Vis) study, the interaction of pentaphosphaferrocene [Cp*Fe(η(5) -P5 )] with trimeric copper pyrazolate [(Cu{3,5-(CF3 )2 Pz})3 ] yields a new compound that is astonishingly stable in solution. Single-crystal X-ray analysis reveals unprecedented structural changes in the interacting molecules and the unique type of coordination [Cp*Fe(μ3 -η(5) :η(2) ,η(2) -P5 ){Cu(3,5-(CF3 )2 Pz)}3 ]. As a result of the 90° macrocycle folding, the copper atoms are able to behave both as a Lewis acid and as a Lewis base in the interaction with the cyclo-P5 ligand.
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Filippov O. A. et al. Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene // Chemistry - A European Journal. 2015. Vol. 21. No. 38. pp. 13176-13180.
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Filippov O. A., Titov A. A., Guseva E. A., Loginov D. A., Smol’yakov A. F., Dolgushin F., belkova N. V., epstein L. M., Shubina E. S. Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene // Chemistry - A European Journal. 2015. Vol. 21. No. 38. pp. 13176-13180.
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RIS
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TY - JOUR
DO - 10.1002/chem.201502085
UR - https://doi.org/10.1002/chem.201502085
TI - Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene
T2 - Chemistry - A European Journal
AU - Filippov, Oleg A.
AU - Titov, Aleksei A
AU - Guseva, Ekaterina A
AU - Loginov, Dmitry A.
AU - Smol’yakov, Alexander F.
AU - Dolgushin, Fedor
AU - belkova, Natalia V.
AU - epstein, Lina M.
AU - Shubina, Elena S.
PY - 2015
DA - 2015/07/27
PB - Wiley
SP - 13176-13180
IS - 38
VL - 21
PMID - 26332228
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
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@article{2015_Filippov,
author = {Oleg A. Filippov and Aleksei A Titov and Ekaterina A Guseva and Dmitry A. Loginov and Alexander F. Smol’yakov and Fedor Dolgushin and Natalia V. belkova and Lina M. epstein and Elena S. Shubina},
title = {Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene},
journal = {Chemistry - A European Journal},
year = {2015},
volume = {21},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/chem.201502085},
number = {38},
pages = {13176--13180},
doi = {10.1002/chem.201502085}
}
Cite this
MLA
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Filippov, Oleg A., et al. “Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene.” Chemistry - A European Journal, vol. 21, no. 38, Jul. 2015, pp. 13176-13180. https://doi.org/10.1002/chem.201502085.