volume 22 issue 40 pages 14190-14194

Oxidative Annulation of Arenecarboxylic and Acrylic Acids with Alkynes under Ambient Conditions Catalyzed by an Electron‐Deficient Rhodium(III) Complex

Eiji Kudo 1
Yu Shibata 1
Mutsumi Yamazaki 2
Koji Masutomi 1
Yuta Miyauchi 1
Miho Fukui 1, 2
Haruki Sugiyama 3
Hidehiro Uekusa 3
Tetsuya Satoh 4, 5
Masahiro Miura 4
Ken Tanaka 1, 2
Publication typeJournal Article
Publication date2016-08-17
scimago Q1
wos Q2
SJR0.981
CiteScore6.7
Impact factor3.7
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract

It has been established that an electron‐deficient CpE rhodium(III) complex catalyzes the oxidative [4+2] annulation of substituted arenecarboxylic and acrylic acids with alkynes under ambient conditions (at RT–40 °C, under air) without using excess amounts of substrates to produce the corresponding substituted isocoumarins and α‐pyrones in high yields. Minor modification of reaction conditions depending on the coordination ability of alkynes realized the high efficiency.

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GOST Copy
Kudo E. et al. Oxidative Annulation of Arenecarboxylic and Acrylic Acids with Alkynes under Ambient Conditions Catalyzed by an Electron‐Deficient Rhodium(III) Complex // Chemistry - A European Journal. 2016. Vol. 22. No. 40. pp. 14190-14194.
GOST all authors (up to 50) Copy
Kudo E., Shibata Yu., Yamazaki M., Masutomi K., Miyauchi Y., Fukui M., Sugiyama H., Uekusa H., Satoh T., Miura M., Tanaka K. Oxidative Annulation of Arenecarboxylic and Acrylic Acids with Alkynes under Ambient Conditions Catalyzed by an Electron‐Deficient Rhodium(III) Complex // Chemistry - A European Journal. 2016. Vol. 22. No. 40. pp. 14190-14194.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/chem.201603499
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201603499
TI - Oxidative Annulation of Arenecarboxylic and Acrylic Acids with Alkynes under Ambient Conditions Catalyzed by an Electron‐Deficient Rhodium(III) Complex
T2 - Chemistry - A European Journal
AU - Kudo, Eiji
AU - Shibata, Yu
AU - Yamazaki, Mutsumi
AU - Masutomi, Koji
AU - Miyauchi, Yuta
AU - Fukui, Miho
AU - Sugiyama, Haruki
AU - Uekusa, Hidehiro
AU - Satoh, Tetsuya
AU - Miura, Masahiro
AU - Tanaka, Ken
PY - 2016
DA - 2016/08/17
PB - Wiley
SP - 14190-14194
IS - 40
VL - 22
PMID - 27459131
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Kudo,
author = {Eiji Kudo and Yu Shibata and Mutsumi Yamazaki and Koji Masutomi and Yuta Miyauchi and Miho Fukui and Haruki Sugiyama and Hidehiro Uekusa and Tetsuya Satoh and Masahiro Miura and Ken Tanaka},
title = {Oxidative Annulation of Arenecarboxylic and Acrylic Acids with Alkynes under Ambient Conditions Catalyzed by an Electron‐Deficient Rhodium(III) Complex},
journal = {Chemistry - A European Journal},
year = {2016},
volume = {22},
publisher = {Wiley},
month = {aug},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201603499},
number = {40},
pages = {14190--14194},
doi = {10.1002/chem.201603499}
}
MLA
Cite this
MLA Copy
Kudo, Eiji, et al. “Oxidative Annulation of Arenecarboxylic and Acrylic Acids with Alkynes under Ambient Conditions Catalyzed by an Electron‐Deficient Rhodium(III) Complex.” Chemistry - A European Journal, vol. 22, no. 40, Aug. 2016, pp. 14190-14194. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201603499.