Hydrogen dissociation catalyzed by carbon-coated nickel nanoparticles: Experiment and theory
Anatoliy Ye Yermakov
1
,
Michael A Uimin
1
,
Ekaterina S Lokteva
3
,
Alexey V Erokhin
3
,
Nina N Schegoleva
1
Publication type: Journal Article
Publication date: 2013-01-04
scimago Q2
wos Q3
SJR: 0.553
CiteScore: 3.6
Impact factor: 2.2
ISSN: 14394235, 14397641
PubMed ID:
23292828
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
Abstract
Based on the combination of experimental measurements and first-principles calculations we report a novel carbon-based catalytic material and describe significant acceleration of the hydrogenation of magnesium at room temperature in the presence of nickel nanoparticles wrapped in multilayer graphene. The increase in rate of magnesium hydrogenation in contrast to a mix of graphite and nickel nanoparticles evidences intrinsic catalytic properties of the nanocomposites explored. The results from simulation demonstrate that doping of the metal substrate and the presence of Stone-Wales defects turn multilayer graphene from being chemically inert to chemically active. The role of the size of the nanoparticles and temperature are also discussed.
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Total citations:
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Citations from 2024:
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GOST
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Yermakov A. Y. et al. Hydrogen dissociation catalyzed by carbon-coated nickel nanoparticles: Experiment and theory // ChemPhysChem. 2013. Vol. 14. No. 2. pp. 381-385.
GOST all authors (up to 50)
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Yermakov A. Y., Boukhvalov D. W., Uimin M. A., Lokteva E. S., Erokhin A. V., Schegoleva N. N. Hydrogen dissociation catalyzed by carbon-coated nickel nanoparticles: Experiment and theory // ChemPhysChem. 2013. Vol. 14. No. 2. pp. 381-385.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/cphc.201200831
UR - https://doi.org/10.1002/cphc.201200831
TI - Hydrogen dissociation catalyzed by carbon-coated nickel nanoparticles: Experiment and theory
T2 - ChemPhysChem
AU - Yermakov, Anatoliy Ye
AU - Boukhvalov, Danil W.
AU - Uimin, Michael A
AU - Lokteva, Ekaterina S
AU - Erokhin, Alexey V
AU - Schegoleva, Nina N
PY - 2013
DA - 2013/01/04
PB - Wiley
SP - 381-385
IS - 2
VL - 14
PMID - 23292828
SN - 1439-4235
SN - 1439-7641
ER -
Cite this
BibTex (up to 50 authors)
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@article{2013_Yermakov,
author = {Anatoliy Ye Yermakov and Danil W. Boukhvalov and Michael A Uimin and Ekaterina S Lokteva and Alexey V Erokhin and Nina N Schegoleva},
title = {Hydrogen dissociation catalyzed by carbon-coated nickel nanoparticles: Experiment and theory},
journal = {ChemPhysChem},
year = {2013},
volume = {14},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/cphc.201200831},
number = {2},
pages = {381--385},
doi = {10.1002/cphc.201200831}
}
Cite this
MLA
Copy
Yermakov, Anatoliy Ye, et al. “Hydrogen dissociation catalyzed by carbon-coated nickel nanoparticles: Experiment and theory.” ChemPhysChem, vol. 14, no. 2, Jan. 2013, pp. 381-385. https://doi.org/10.1002/cphc.201200831.
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