ChemPlusChem, volume 79, issue 9, pages 1278-1283
Palladium Nanoparticles Supported on Poly(N-vinyl- imidazole-co-N-vinylcaprolactam) as an Effective Recyclable Catalyst for the Suzuki Reaction
Publication type: Journal Article
Publication date: 2014-06-11
General Chemistry
Abstract
A recyclable and effective polymer-immobilized ligandless palladium catalyst for the Suzuki reaction has been investigated. Palladium nanoparticles are formed in situ and stabilized by poly(N-vinylimidazole-co-N-vinylcaprolactam). A series of aryl bromides have been studied in the reaction with phenylboronic acid under mild conditions with water–alcohol systems as a solvent that complies with “Green Chemistry” demands. The catalyst can be recycled eight times without appreciable loss in activity and a low degree of palladium leaching. Kinetic studies reveal unusual behavior of the reaction; this can be explained on the basis of the observation of changes to the sizes of the particles during recycling, as determined by TEM results. The suggested mechanism of the reaction is in accordance with the concept of the role of leaching in the process.
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1 publication, 4.76%
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1 publication, 4.76%
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1 publication, 4.76%
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Citations by publishers
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Royal Society of Chemistry (RSC)
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5 publications, 23.81%
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American Chemical Society (ACS)
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4 publications, 19.05%
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3 publications, 14.29%
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2 publications, 9.52%
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Springer Nature
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Springer Nature
1 publication, 4.76%
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Walter de Gruyter
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1 publication, 4.76%
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Irkutsk National Research Technical University
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Irkutsk National Research Technical University
1 publication, 4.76%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 4.76%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Selivanova A. V., Tyurin V. S., Beletskaya I. P. Palladium Nanoparticles Supported on Poly(N-vinyl- imidazole-co-N-vinylcaprolactam) as an Effective Recyclable Catalyst for the Suzuki Reaction // ChemPlusChem. 2014. Vol. 79. No. 9. pp. 1278-1283.
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Selivanova A. V., Tyurin V. S., Beletskaya I. P. Palladium Nanoparticles Supported on Poly(N-vinyl- imidazole-co-N-vinylcaprolactam) as an Effective Recyclable Catalyst for the Suzuki Reaction // ChemPlusChem. 2014. Vol. 79. No. 9. pp. 1278-1283.
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TY - JOUR
DO - 10.1002/cplu.201402111
UR - https://doi.org/10.1002%2Fcplu.201402111
TI - Palladium Nanoparticles Supported on Poly(N-vinyl- imidazole-co-N-vinylcaprolactam) as an Effective Recyclable Catalyst for the Suzuki Reaction
T2 - ChemPlusChem
AU - Selivanova, Alexandra V
AU - Tyurin, Vladimir S
AU - Beletskaya, Irina P.
PY - 2014
DA - 2014/06/11 00:00:00
PB - Wiley
SP - 1278-1283
IS - 9
VL - 79
SN - 2192-6506
ER -
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@article{2014_Selivanova,
author = {Alexandra V Selivanova and Vladimir S Tyurin and Irina P. Beletskaya},
title = {Palladium Nanoparticles Supported on Poly(N-vinyl- imidazole-co-N-vinylcaprolactam) as an Effective Recyclable Catalyst for the Suzuki Reaction},
journal = {ChemPlusChem},
year = {2014},
volume = {79},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002%2Fcplu.201402111},
number = {9},
pages = {1278--1283},
doi = {10.1002/cplu.201402111}
}
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Selivanova, Alexandra V., et al. “Palladium Nanoparticles Supported on Poly(N-vinyl- imidazole-co-N-vinylcaprolactam) as an Effective Recyclable Catalyst for the Suzuki Reaction.” ChemPlusChem, vol. 79, no. 9, Jun. 2014, pp. 1278-1283. https://doi.org/10.1002%2Fcplu.201402111.