, volume 2007 , issue 20 , pages 3151-3167

Reactions of Ytterbocenes with Diimines: Steric Manipulation of Reductive Reactivity

Alexander A. Trifonov ¹

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G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, Tropinina 49, 603950, Nizhny Novgorod, GSP‐445, Russia, Fax: +7‐8312‐621497 |

Publication type: Journal Article

Publication date: 2007-07-01

Wiley

European Journal of Inorganic Chemistry

scimago Q2

wos Q3

SJR: 0.459

CiteScore: 3.9

Impact factor: 2.0

ISSN: 14341948, 10990682

DOI: 10.1002/ejic.200601209

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Inorganic Chemistry

Abstract

This review is devoted to the investigation of reactions of ytterbocenes with diimines. These reactions are found to be strongly influenced by the steric crowding in the coordination sphere of the metal atom and the coordination capacities of π-aromatic ligands coordinated to the ytterbium. The reactions may occur with oxidation of the ytterbium atom as well as with retention of its oxidation state. C–C bond formation, C–H bond activation, C=N bond insertion, and oxidative Yb–C bond cleavage processes are documented for reactions of ytterbocenes with diimines. Steric overcrowding of the coordination sphere of the ytterbium atom can induce “extra” reducing ability of ytterbocenes and allow them to act not only as one- but also as two-electron reductants with respect to diimines. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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14 citations

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DSc in Chemistry, associate professor, professor of the Russian Academy of Sciences

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Trifonov A. A. Reactions of Ytterbocenes with Diimines: Steric Manipulation of Reductive Reactivity // European Journal of Inorganic Chemistry. 2007. Vol. 2007. No. 20. pp. 3151-3167.

GOST all authors (up to 50) Copy

Trifonov A. A. Reactions of Ytterbocenes with Diimines: Steric Manipulation of Reductive Reactivity // European Journal of Inorganic Chemistry. 2007. Vol. 2007. No. 20. pp. 3151-3167.

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RIS Copy

TY - JOUR

DO - 10.1002/ejic.200601209

UR - https://doi.org/10.1002/ejic.200601209

TI - Reactions of Ytterbocenes with Diimines: Steric Manipulation of Reductive Reactivity

T2 - European Journal of Inorganic Chemistry

AU - Trifonov, Alexander A.

PY - 2007

DA - 2007/07/01

PB - Wiley

SP - 3151-3167

IS - 20

VL - 2007

SN - 1434-1948

SN - 1099-0682

ER -

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@article{2007_Trifonov,

author = {Alexander A. Trifonov},

title = {Reactions of Ytterbocenes with Diimines: Steric Manipulation of Reductive Reactivity},

journal = {European Journal of Inorganic Chemistry},

year = {2007},

volume = {2007},

publisher = {Wiley},

month = {jul},

url = {https://doi.org/10.1002/ejic.200601209},

number = {20},

pages = {3151--3167},

doi = {10.1002/ejic.200601209}

}

MLA

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Trifonov, Alexander A.. “Reactions of Ytterbocenes with Diimines: Steric Manipulation of Reductive Reactivity.” European Journal of Inorganic Chemistry, vol. 2007, no. 20, Jul. 2007, pp. 3151-3167. https://doi.org/10.1002/ejic.200601209.