Topology Control of Porous Coordination Polymers by Building Block Symmetry
Ruslan A. Polunin
1
,
Mikhail A Kiskin
2
,
Igor L. Eremenko
2
,
Sergey V Kolotilov
1
,
Olivier Cador
3
,
Elena A. Mikhalyova
1
,
Anton S Lytvynenko
1
,
Stéphane Golhen
3
,
Lahcène Ouahab
3
,
Vladimir M. Novotortsev
2
,
Vitaly V. Pavlishchuk
1
,
Victor I Ovcharenko
4
1
L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of the Ukraine, Prospekt Nauki 31, Kiev 03028, Ukraine, Fax: +38‐044‐5256216
|
Publication type: Journal Article
Publication date: 2010-10-11
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
The coordination polymers [Fe 2 MO(piv) 6 (bipy) 1.5 ] n [M = Ni II , compound 1, and M = Co", compound 2; piv = (CH 3 ) 3 CCO 2 ― and bipy = 4,4'-bipyridine] were prepared by linking trinuclear heterometallic pivalates, possessing D 3h symmetry, by linear molecules of bipy. The complexes are isostructural and are built from 2D doubly interpenetrated "honeycomb" layers. The structure of the starting polynuclear building blocks is retained, which opens the way for the creation of materials with predetermined properties. Zigzag channels in the crystal structures of the compounds can adsorb N 2 and H 2 . Unusual N 2 adsorption/desorption hysteresis was observed. Magnetic properties of the polymers are governed by exchange interactions in trinuclear blocks. The χ M T vs. T curve for 2 was fitted by taking into account the zero-field splitting of the Co II ion by using software specially developed for this purpose.
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Citations from 2024:
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GOST
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Kiskin M. A. et al. Topology Control of Porous Coordination Polymers by Building Block Symmetry // European Journal of Inorganic Chemistry. 2010. Vol. 2010. No. 32. pp. 5055-5057.
GOST all authors (up to 50)
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Polunin R. A., Kiskin M. A., Eremenko I. L., Kolotilov S. V., Cador O., Mikhalyova E. A., Lytvynenko A. S., Golhen S., Ouahab L., Novotortsev V. M., Pavlishchuk V. V., Ovcharenko V. I. Topology Control of Porous Coordination Polymers by Building Block Symmetry // European Journal of Inorganic Chemistry. 2010. Vol. 2010. No. 32. pp. 5055-5057.
Cite this
RIS
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TY - JOUR
DO - 10.1002/ejic.201000929
UR - https://doi.org/10.1002/ejic.201000929
TI - Topology Control of Porous Coordination Polymers by Building Block Symmetry
T2 - European Journal of Inorganic Chemistry
AU - Polunin, Ruslan A.
AU - Kiskin, Mikhail A
AU - Eremenko, Igor L.
AU - Kolotilov, Sergey V
AU - Cador, Olivier
AU - Mikhalyova, Elena A.
AU - Lytvynenko, Anton S
AU - Golhen, Stéphane
AU - Ouahab, Lahcène
AU - Novotortsev, Vladimir M.
AU - Pavlishchuk, Vitaly V.
AU - Ovcharenko, Victor I
PY - 2010
DA - 2010/10/11
PB - Wiley
SP - 5055-5057
IS - 32
VL - 2010
SN - 1434-1948
SN - 1099-0682
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Kiskin,
author = {Ruslan A. Polunin and Mikhail A Kiskin and Igor L. Eremenko and Sergey V Kolotilov and Olivier Cador and Elena A. Mikhalyova and Anton S Lytvynenko and Stéphane Golhen and Lahcène Ouahab and Vladimir M. Novotortsev and Vitaly V. Pavlishchuk and Victor I Ovcharenko},
title = {Topology Control of Porous Coordination Polymers by Building Block Symmetry},
journal = {European Journal of Inorganic Chemistry},
year = {2010},
volume = {2010},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/ejic.201000929},
number = {32},
pages = {5055--5057},
doi = {10.1002/ejic.201000929}
}
Cite this
MLA
Copy
Kiskin, Mikhail A., et al. “Topology Control of Porous Coordination Polymers by Building Block Symmetry.” European Journal of Inorganic Chemistry, vol. 2010, no. 32, Oct. 2010, pp. 5055-5057. https://doi.org/10.1002/ejic.201000929.
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