Wiley
European Journal of Inorganic Chemistry
,  volume 2018 ,  issue 22 ,  pages 2505-2511

Heptanuclear Cage Cu II ‐Silsesquioxanes: Synthesis, Structure and Catalytic Activity

Alexey N Bilyachenko 1, 2
, 
Mikhail M Levitsky 1
, 
Alexander Korlyukov 3, 4
, 
Alexander A. Korlyukov 1, 5
, 
Victor N. Khrustalev 6
, 
Yan V. Zubavichus 7
, 
Georgiy B. Shul'pin 1
, 
Elena S. Shubina 3
, 
A. Vologzhanina 3
, 
Anna V. Vologzhanina 1
, 
Georgiy B Shulpin 8, 9
1
 
2
 
3
 
4
 
5
 
6
 
7
 
8
 
9
 
Publication type: Journal Article
Publication date: 2018-04-14
Wiley
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract

Two prismatic phenyl‐ (PhSiO1.5)14(CuO)7 (1, 29 % yield) and methyl‐ (MeSiO1.5)14(CuO)7 (2, 19 % yield) heptacoppersilsesquioxanes were obtained by the interaction of Cu,Na‐based cage silsesquioxanes [(RSiO1.5)12(CuO)4(NaO0.5)4] (R = Ph, Me) with 4,4′‐bipyridine and pyrazine, respectively, acting as “silent witness” ligands. Unusual molecular topologies of both compounds 1 and 2, which are the first representatives of cage silsesquioxanes with seven metal ions in their cores, were established by X‐ray diffraction studies. Complex 1 was found to be an active precatalyst in the oxidation of alkanes and 1‐phenylethanol to alkyl hydroperoxides and acetophenone, respectively. Alkanes were oxidized by hydrogen peroxide, and the alcohol was oxidized by tert‐butyl hydroperoxide.

Found 
Found 
14 citations
Bilyachenko Alexey
🥼 🤝
DSc in Chemistry
88 publications,  2 089 citations,  13 reviews
h-index: 28
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Peoples' Friendship University of Russia
Peoples' Friendship University of Russia
13 citations
Shubina Elena
DSc in Chemistry, professor
264 publications,  5 882 citations,  16 reviews
h-index: 38
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Molecular spectroscopy
7 citations
Khrustalev Victor
DSc in Chemistry, professor, professor of the Russian Academy of Sciences 
326 publications,  4 094 citations,  4 reviews
h-index: 30
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
Peoples' Friendship University of Russia
Peoples' Friendship University of Russia
7 citations
Dorovatovskii Pavel
340 publications,  4 036 citations
h-index: 28
National Research Centre "Kurchatov Institute"
National Research Centre "Kurchatov Institute"
5 citations
Astakhov Grigorii
🤝
PhD in Chemistry
14 publications,  281 citations
h-index: 12
Shandong University
Shandong University
Research interests
"Smart" materials
Catalysis
Coordination Chemistry
Green chemistry
Inorganic Chemistry
Metal-organic coordination polymers
Organoelement chemistry
Organometallic Chemistry
1 citation
Nelyubina Yulia
🤝
DSc in Chemistry
506 publications,  7 606 citations,  1 review
h-index: 38
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Moscow Institute of Physics and Technology
Moscow Institute of Physics and Technology
Research interests
Big Data
Catalysis
Machine learning
Metal-organic frameworks
Quantum technologies
Sensors

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Bilyachenko A. N. et al. Heptanuclear Cage Cu II ‐Silsesquioxanes: Synthesis, Structure and Catalytic Activity // European Journal of Inorganic Chemistry. 2018. Vol. 2018. No. 22. pp. 2505-2511.
GOST all authors (up to 50) Copy
Bilyachenko A. N., Levitsky M. M., Korlyukov A., Korlyukov A. A., Khrustalev V. N., Zubavichus Y. V., Shul'pin G. B., Shubina E. S., Vologzhanina A., Vologzhanina A. V., Shulpin G. B. Heptanuclear Cage Cu II ‐Silsesquioxanes: Synthesis, Structure and Catalytic Activity // European Journal of Inorganic Chemistry. 2018. Vol. 2018. No. 22. pp. 2505-2511.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/ejic.201701340
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201701340
TI - Heptanuclear Cage Cu II ‐Silsesquioxanes: Synthesis, Structure and Catalytic Activity
T2 - European Journal of Inorganic Chemistry
AU - Bilyachenko, Alexey N
AU - Levitsky, Mikhail M
AU - Korlyukov, Alexander
AU - Korlyukov, Alexander A.
AU - Khrustalev, Victor N.
AU - Zubavichus, Yan V.
AU - Shul'pin, Georgiy B.
AU - Shubina, Elena S.
AU - Vologzhanina, A.
AU - Vologzhanina, Anna V.
AU - Shulpin, Georgiy B
PY - 2018
DA - 2018/04/14
PB - Wiley
SP - 2505-2511
IS - 22
VL - 2018
SN - 1434-1948
SN - 1099-0682
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Bilyachenko,
author = {Alexey N Bilyachenko and Mikhail M Levitsky and Alexander Korlyukov and Alexander A. Korlyukov and Victor N. Khrustalev and Yan V. Zubavichus and Georgiy B. Shul'pin and Elena S. Shubina and A. Vologzhanina and Anna V. Vologzhanina and Georgiy B Shulpin},
title = {Heptanuclear Cage Cu II ‐Silsesquioxanes: Synthesis, Structure and Catalytic Activity},
journal = {European Journal of Inorganic Chemistry},
year = {2018},
volume = {2018},
publisher = {Wiley},
month = {apr},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201701340},
number = {22},
pages = {2505--2511},
doi = {10.1002/ejic.201701340}
}
MLA
Cite this
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Bilyachenko, Alexey N., et al. “Heptanuclear Cage Cu II ‐Silsesquioxanes: Synthesis, Structure and Catalytic Activity.” European Journal of Inorganic Chemistry, vol. 2018, no. 22, Apr. 2018, pp. 2505-2511. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201701340.