Dinuclear CuI and AgI Pyrazolates Supported with Tertiary Phosphines: Synthesis, Structures, and Photophysical Properties
Aleksei A Titov
1
,
Oleg A. Filippov
1
,
Alexander F. Smol’yakov
1, 2
,
Kristina F Baranova
1, 3
,
Ekaterina Titova
1, 2
,
Aleksey A Averin
4
,
Publication type: Journal Article
Publication date: 2019-01-15
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
New dinuclear silver(I) and copper(I) 3,5‐bis(trifluoromethyl)pyrazolate compounds were prepared by the reaction of the corresponding trinuclear metal complexes with tertiary phosphines (PPh3, PCy3). In the case of copper(I) trinuclear pyrazolate it was shown that the product structure depends on the reagent ratio: mono‐ and dinuclear complexes were obtained. All the dinuclear complexes obtained exhibit light emission in the solid state under UV irradiation. The observed photoluminescence behavior was confirmed by the TD‐DFT study.
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Total citations:
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Citations from 2024:
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(13.64%)
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GOST
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Titov A. A. et al. Dinuclear CuI and AgI Pyrazolates Supported with Tertiary Phosphines: Synthesis, Structures, and Photophysical Properties // European Journal of Inorganic Chemistry. 2019. Vol. 2019. No. 6. pp. 821-827.
GOST all authors (up to 50)
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Titov A. A., Filippov O. A., Smol’yakov A. F., Baranova K. F., Titova E., Averin A. A., Shubina E. S. Dinuclear CuI and AgI Pyrazolates Supported with Tertiary Phosphines: Synthesis, Structures, and Photophysical Properties // European Journal of Inorganic Chemistry. 2019. Vol. 2019. No. 6. pp. 821-827.
Cite this
RIS
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TY - JOUR
DO - 10.1002/ejic.201801318
UR - https://doi.org/10.1002/ejic.201801318
TI - Dinuclear CuI and AgI Pyrazolates Supported with Tertiary Phosphines: Synthesis, Structures, and Photophysical Properties
T2 - European Journal of Inorganic Chemistry
AU - Titov, Aleksei A
AU - Filippov, Oleg A.
AU - Smol’yakov, Alexander F.
AU - Baranova, Kristina F
AU - Titova, Ekaterina
AU - Averin, Aleksey A
AU - Shubina, Elena S.
PY - 2019
DA - 2019/01/15
PB - Wiley
SP - 821-827
IS - 6
VL - 2019
SN - 1434-1948
SN - 1099-0682
ER -
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BibTex (up to 50 authors)
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@article{2019_Titov,
author = {Aleksei A Titov and Oleg A. Filippov and Alexander F. Smol’yakov and Kristina F Baranova and Ekaterina Titova and Aleksey A Averin and Elena S. Shubina},
title = {Dinuclear CuI and AgI Pyrazolates Supported with Tertiary Phosphines: Synthesis, Structures, and Photophysical Properties},
journal = {European Journal of Inorganic Chemistry},
year = {2019},
volume = {2019},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/ejic.201801318},
number = {6},
pages = {821--827},
doi = {10.1002/ejic.201801318}
}
Cite this
MLA
Copy
Titov, Aleksei A., et al. “Dinuclear CuI and AgI Pyrazolates Supported with Tertiary Phosphines: Synthesis, Structures, and Photophysical Properties.” European Journal of Inorganic Chemistry, vol. 2019, no. 6, Jan. 2019, pp. 821-827. https://doi.org/10.1002/ejic.201801318.
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