Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H 2 Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes
Nikolay V Kireev
1
,
Alexandra V. Yurkovskaya
2
,
Elvira Musina
3
,
Andrey A Karasik
3
,
Elena S. Shubina
1
,
V. Ivanov Konstantin
2
,
Publication type: Journal Article
Publication date: 2021-08-26
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
Reversible binding of H2 is shown for nickel complexes yielding the products of dihydrogen heterolytic splitting [NiH(PR12NR22)(PR12NR22H)]2+ (P2N2=1,5-diaza-3,7-diphosphacyclooctane) whose intermediacy in the reaction has been only anticipated so far. With the help of NMR spectroscopy and parahydrogen induced polarization, the formation of [Ni(η2−H2)(PR12NR22)2]2+ complex was detected for the first time with R1=Ph, R2=Ph2CH.
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21
Total citations:
21
Citations from 2024:
10
(47.62%)
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GOST
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Kireev N. V. et al. Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H 2 Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes // European Journal of Inorganic Chemistry. 2021. Vol. 2021. No. 41. pp. 4265-4272.
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Kireev N. V., Kiryutin A. S., Pavlov A. A., Yurkovskaya A. V., Musina E., Karasik A. A., Shubina E. S., Konstantin V. I., Belkova N. V. Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H 2 Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes // European Journal of Inorganic Chemistry. 2021. Vol. 2021. No. 41. pp. 4265-4272.
Cite this
RIS
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TY - JOUR
DO - 10.1002/ejic.202100489
UR - https://doi.org/10.1002/ejic.202100489
TI - Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H 2 Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes
T2 - European Journal of Inorganic Chemistry
AU - Kireev, Nikolay V
AU - Kiryutin, Alexey S.
AU - Pavlov, Alexander A
AU - Yurkovskaya, Alexandra V.
AU - Musina, Elvira
AU - Karasik, Andrey A
AU - Shubina, Elena S.
AU - Konstantin, V. Ivanov
AU - Belkova, Natalia V
PY - 2021
DA - 2021/08/26
PB - Wiley
SP - 4265-4272
IS - 41
VL - 2021
SN - 1434-1948
SN - 1099-0682
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Kireev,
author = {Nikolay V Kireev and Alexey S. Kiryutin and Alexander A Pavlov and Alexandra V. Yurkovskaya and Elvira Musina and Andrey A Karasik and Elena S. Shubina and V. Ivanov Konstantin and Natalia V Belkova},
title = {Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H 2 Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes},
journal = {European Journal of Inorganic Chemistry},
year = {2021},
volume = {2021},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/ejic.202100489},
number = {41},
pages = {4265--4272},
doi = {10.1002/ejic.202100489}
}
Cite this
MLA
Copy
Kireev, Nikolay V., et al. “Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H 2 Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes.” European Journal of Inorganic Chemistry, vol. 2021, no. 41, Aug. 2021, pp. 4265-4272. https://doi.org/10.1002/ejic.202100489.