Unusual influence of the structures of transition metal complexes on catalytic C-S and C-Se bond formation under homogeneous and heterogeneous conditions
Publication type: Journal Article
Publication date: 2007-07-01
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
In the presence of transition metal catalysts, hydrothiolation and hydroselenation reactions, as well as bisthiolation and bisselenation reactions, have been successfully carried out with high selectivities and yields. New transition metal-catalyzed synthetic methods have been developed for the preparation of vinyl sulfides and vinyl selenides of various types. Mechanistic study has revealed that a homogeneous catalytic system based on phosphine complexes of palladium is the best choice for carrying out stereoselective additions of disulfides and diselenides to alkynes. A heterogeneous Ni-catalyzed reaction with a unique self-organized nanostructured catalyst was superior for carrying out regioselective additions of thiols and selenols to alkynes.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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197
Total citations:
197
Citations from 2024:
7
(3%)
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Beletskaya I. P., Ananikov V. P. Unusual influence of the structures of transition metal complexes on catalytic C-S and C-Se bond formation under homogeneous and heterogeneous conditions // European Journal of Organic Chemistry. 2007. Vol. 2007. No. 21. pp. 3431-3444.
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Beletskaya I. P., Ananikov V. P. Unusual influence of the structures of transition metal complexes on catalytic C-S and C-Se bond formation under homogeneous and heterogeneous conditions // European Journal of Organic Chemistry. 2007. Vol. 2007. No. 21. pp. 3431-3444.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/ejoc.200700119
UR - https://doi.org/10.1002/ejoc.200700119
TI - Unusual influence of the structures of transition metal complexes on catalytic C-S and C-Se bond formation under homogeneous and heterogeneous conditions
T2 - European Journal of Organic Chemistry
AU - Beletskaya, Irina P.
AU - Ananikov, Valentine P.
PY - 2007
DA - 2007/07/01
PB - Wiley
SP - 3431-3444
IS - 21
VL - 2007
SN - 1434-193X
SN - 1099-0690
ER -
Cite this
BibTex (up to 50 authors)
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@article{2007_Beletskaya,
author = {Irina P. Beletskaya and Valentine P. Ananikov},
title = {Unusual influence of the structures of transition metal complexes on catalytic C-S and C-Se bond formation under homogeneous and heterogeneous conditions},
journal = {European Journal of Organic Chemistry},
year = {2007},
volume = {2007},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/ejoc.200700119},
number = {21},
pages = {3431--3444},
doi = {10.1002/ejoc.200700119}
}
Cite this
MLA
Copy
Beletskaya, Irina P., and Valentine P. Ananikov. “Unusual influence of the structures of transition metal complexes on catalytic C-S and C-Se bond formation under homogeneous and heterogeneous conditions.” European Journal of Organic Chemistry, vol. 2007, no. 21, Jul. 2007, pp. 3431-3444. https://doi.org/10.1002/ejoc.200700119.
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