Access to Cyclic α-CF3-Substituted α-Amino Acid Derivatives by Ring-Closing Metathesis of Functionalized 1,7-Enynes
Publication type: Journal Article
Publication date: 2013-07-10
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
An efficient method for the preparation of new α-CF3 α-amino acid 1,7-enynes that contain electron-donating and electron-withdrawing groups on the triple bond has been developed that proceeds through a Sonogashira-type coupling reaction. The ring-closing enyne methathesis (RCEYM) of the obtained 1,7-enynes with commercially available Grubbs and Hoveyda catalysts provides access to a series of new cyclic α-amino acids. The latter compounds that contain the 1,3-diene moiety are attractive building blocks for the construction of trifluoromethylated polycyclic systems.
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Total citations:
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Citations from 2025:
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(3.7%)
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GOST
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Mailyan A. K. et al. Access to Cyclic α-CF3-Substituted α-Amino Acid Derivatives by Ring-Closing Metathesis of Functionalized 1,7-Enynes // European Journal of Organic Chemistry. 2013. Vol. 2013. No. 24. pp. 5353-5363.
GOST all authors (up to 50)
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Mailyan A. K., Krylov I. M., Bruneau C., Dixneuf P. H., Osipov S. N. Access to Cyclic α-CF3-Substituted α-Amino Acid Derivatives by Ring-Closing Metathesis of Functionalized 1,7-Enynes // European Journal of Organic Chemistry. 2013. Vol. 2013. No. 24. pp. 5353-5363.
Cite this
RIS
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TY - JOUR
DO - 10.1002/ejoc.201300619
UR - https://doi.org/10.1002/ejoc.201300619
TI - Access to Cyclic α-CF3-Substituted α-Amino Acid Derivatives by Ring-Closing Metathesis of Functionalized 1,7-Enynes
T2 - European Journal of Organic Chemistry
AU - Mailyan, Artur K
AU - Krylov, Ivan M
AU - Bruneau, Christian
AU - Dixneuf, Pierre H.
AU - Osipov, Sergey N.
PY - 2013
DA - 2013/07/10
PB - Wiley
SP - 5353-5363
IS - 24
VL - 2013
SN - 1434-193X
SN - 1099-0690
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Mailyan,
author = {Artur K Mailyan and Ivan M Krylov and Christian Bruneau and Pierre H. Dixneuf and Sergey N. Osipov},
title = {Access to Cyclic α-CF3-Substituted α-Amino Acid Derivatives by Ring-Closing Metathesis of Functionalized 1,7-Enynes},
journal = {European Journal of Organic Chemistry},
year = {2013},
volume = {2013},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/ejoc.201300619},
number = {24},
pages = {5353--5363},
doi = {10.1002/ejoc.201300619}
}
Cite this
MLA
Copy
Mailyan, Artur K., et al. “Access to Cyclic α-CF3-Substituted α-Amino Acid Derivatives by Ring-Closing Metathesis of Functionalized 1,7-Enynes.” European Journal of Organic Chemistry, vol. 2013, no. 24, Jul. 2013, pp. 5353-5363. https://doi.org/10.1002/ejoc.201300619.
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