Wiley
European Journal of Organic Chemistry
,  volume 2015 ,  issue 22 ,  pages 4950-4955

CF3-Carbenoid C-H Functionalization of (Hetero)arenes under Chelation-Controlled RhIIICatalysis

Publication type: Journal Article
Publication date: 2015-06-24
Wiley
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
An efficient method for the CF3-carbenoid C–H functionalization of benzenes and indoles using readily available methyl 3,3,3-trifluoro-2-diazopropionate as a cross-coupling partner under chelation-controlled RhIII catalysis has been developed. The reactions proceeded smoothly with high regioselectivity in a few hours and allowed the simultaneous introduction of CF3 and carboxylate functions into the 2-position of directing-group-containing benzenes and indoles.
Found 
Found 
3 citations
Nelyubina Yulia
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DSc in Chemistry
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A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Moscow Institute of Physics and Technology
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A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
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Mendeleev University of Chemical Technology of Russia
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Ural Federal University
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GOST |
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GOST Copy
Iagafarova I. E. et al. CF3-Carbenoid C-H Functionalization of (Hetero)arenes under Chelation-Controlled RhIIICatalysis // European Journal of Organic Chemistry. 2015. Vol. 2015. No. 22. pp. 4950-4955.
GOST all authors (up to 50) Copy
Iagafarova I. E., Vorobyeva D. V., Peregudov A. S., Osipov S. N. CF3-Carbenoid C-H Functionalization of (Hetero)arenes under Chelation-Controlled RhIIICatalysis // European Journal of Organic Chemistry. 2015. Vol. 2015. No. 22. pp. 4950-4955.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/ejoc.201500545
UR - https://doi.org/10.1002/ejoc.201500545
TI - CF3-Carbenoid C-H Functionalization of (Hetero)arenes under Chelation-Controlled RhIIICatalysis
T2 - European Journal of Organic Chemistry
AU - Iagafarova, Irina E
AU - Vorobyeva, Daria V
AU - Peregudov, A. S.
AU - Osipov, Sergey N.
PY - 2015
DA - 2015/06/24
PB - Wiley
SP - 4950-4955
IS - 22
VL - 2015
SN - 1434-193X
SN - 1099-0690
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Iagafarova,
author = {Irina E Iagafarova and Daria V Vorobyeva and A. S. Peregudov and Sergey N. Osipov},
title = {CF3-Carbenoid C-H Functionalization of (Hetero)arenes under Chelation-Controlled RhIIICatalysis},
journal = {European Journal of Organic Chemistry},
year = {2015},
volume = {2015},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/ejoc.201500545},
number = {22},
pages = {4950--4955},
doi = {10.1002/ejoc.201500545}
}
MLA
Cite this
MLA Copy
Iagafarova, Irina E., et al. “CF3-Carbenoid C-H Functionalization of (Hetero)arenes under Chelation-Controlled RhIIICatalysis.” European Journal of Organic Chemistry, vol. 2015, no. 22, Jun. 2015, pp. 4950-4955. https://doi.org/10.1002/ejoc.201500545.
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