Wiley
European Journal of Organic Chemistry
,  volume 2017 ,  issue 4 ,  pages 840-845

RhIII-Catalyzed CF3-Carbenoid C-7 Functionalization of Indolines

Publication type: Journal Article
Publication date: 2017-01-26
Wiley
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
An efficient method for CF3-carbenoid C7 functionalization of N-pyrimidylindolines using readily available methyl 3,3,3-trifluoro-2-diazopropionate as a cross-coupling partner under chelation-controlled Rh(III)-catalysis has been developed. The reactions smoothly proceed with high regioselectivity for a few hours and allow introducing CF3 and carboxylate functions simultaneously into C7-position of indolines.
Found 
Found 
9 citations
Osipov Sergey
DSc in Chemistry
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A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
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GOST |
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GOST Copy
Iagafarova I. E. et al. RhIII-Catalyzed CF3-Carbenoid C-7 Functionalization of Indolines // European Journal of Organic Chemistry. 2017. Vol. 2017. No. 4. pp. 840-845.
GOST all authors (up to 50) Copy
Iagafarova I. E., Vorobyeva D. V., Loginov D. A., Peregudov A. S., Osipov S. N. RhIII-Catalyzed CF3-Carbenoid C-7 Functionalization of Indolines // European Journal of Organic Chemistry. 2017. Vol. 2017. No. 4. pp. 840-845.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/ejoc.201601400
UR - https://doi.org/10.1002/ejoc.201601400
TI - RhIII-Catalyzed CF3-Carbenoid C-7 Functionalization of Indolines
T2 - European Journal of Organic Chemistry
AU - Iagafarova, Irina E
AU - Vorobyeva, Daria V
AU - Loginov, Dmitry A.
AU - Peregudov, A. S.
AU - Osipov, Sergey N.
PY - 2017
DA - 2017/01/26
PB - Wiley
SP - 840-845
IS - 4
VL - 2017
SN - 1434-193X
SN - 1099-0690
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Iagafarova,
author = {Irina E Iagafarova and Daria V Vorobyeva and Dmitry A. Loginov and A. S. Peregudov and Sergey N. Osipov},
title = {RhIII-Catalyzed CF3-Carbenoid C-7 Functionalization of Indolines},
journal = {European Journal of Organic Chemistry},
year = {2017},
volume = {2017},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/ejoc.201601400},
number = {4},
pages = {840--845},
doi = {10.1002/ejoc.201601400}
}
MLA
Cite this
MLA Copy
Iagafarova, Irina E., et al. “RhIII-Catalyzed CF3-Carbenoid C-7 Functionalization of Indolines.” European Journal of Organic Chemistry, vol. 2017, no. 4, Jan. 2017, pp. 840-845. https://doi.org/10.1002/ejoc.201601400.