Thermoshrinking behavior of poly(vinylcaprolactam) gels in aqueous solution
Publication type: Journal Article
Publication date: 1996-06-01
scimago Q2
wos Q3
SJR: 0.569
CiteScore: 4.5
Impact factor: 2.7
ISSN: 10221352, 15213935
Materials Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
The swelling of newly synthesized slightly crosslinked gels of polyvinylcaprolactam (PVCa) was studied as a function of temperature. In water, PVCa gels undergo a sharp volume transition from a swollen to a collapsed state on heating. In water/alcohol mixtures, the gel first shrinks and then expands as the temperature is raised. The swelling behavior of the thermosensitive PVCa gel in surfactant solution depends on kind and concentration of the surfactant. Normally, an additional swelling of the gel is observed in the presence of ionic surfactants. Addition of the surfactant raises the collapse transition temperature of the gel. Absorption of the surfactant by the PVCa gel as a function of temperature and surfactant concentration is analysed in detail.
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Total citations:
77
Citations from 2024:
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(1%)
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GOST
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Makhaeva E. E. et al. Thermoshrinking behavior of poly(vinylcaprolactam) gels in aqueous solution // Macromolecular Chemistry and Physics. 1996. Vol. 197. No. 6. pp. 1973-1982.
GOST all authors (up to 50)
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Makhaeva E. E., Thanh L. T. M., Starodoubtsev S. G., Khokhlov A. R. Thermoshrinking behavior of poly(vinylcaprolactam) gels in aqueous solution // Macromolecular Chemistry and Physics. 1996. Vol. 197. No. 6. pp. 1973-1982.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/macp.1996.021970616
UR - https://doi.org/10.1002/macp.1996.021970616
TI - Thermoshrinking behavior of poly(vinylcaprolactam) gels in aqueous solution
T2 - Macromolecular Chemistry and Physics
AU - Makhaeva, Elena E.
AU - Thanh, Le Thi Minh
AU - Starodoubtsev, Sergei G
AU - Khokhlov, Alexei R.
PY - 1996
DA - 1996/06/01
PB - Wiley
SP - 1973-1982
IS - 6
VL - 197
SN - 1022-1352
SN - 1521-3935
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1996_Makhaeva,
author = {Elena E. Makhaeva and Le Thi Minh Thanh and Sergei G Starodoubtsev and Alexei R. Khokhlov},
title = {Thermoshrinking behavior of poly(vinylcaprolactam) gels in aqueous solution},
journal = {Macromolecular Chemistry and Physics},
year = {1996},
volume = {197},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/macp.1996.021970616},
number = {6},
pages = {1973--1982},
doi = {10.1002/macp.1996.021970616}
}
Cite this
MLA
Copy
Makhaeva, Elena E., et al. “Thermoshrinking behavior of poly(vinylcaprolactam) gels in aqueous solution.” Macromolecular Chemistry and Physics, vol. 197, no. 6, Jun. 1996, pp. 1973-1982. https://doi.org/10.1002/macp.1996.021970616.
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