Macromolecular Rapid Communications, volume 43, issue 9, pages 2200060

Novel Pyrrolo [3,4-b] Dithieno [3, 2-f:2″,3″-h] Quinoxaline-8,10 (9H)-Dione Based Wide Bandgap Conjugated Copolymers for Bulk Heterojunction Polymer Solar Cells

Keshtov Mukhamed L ¹

Khokhlov Alexei R. ^{1, 2}

Godovsky Dimitry Y ²

Ostapov Ilya E ¹

Alekseev Vladimir G ³

Xie Zhiyuan ⁴

Chayal Giriraj ⁵

Sharma Ganesh Datt ⁶

Hide authors affiliations Show authors affiliations: 6 affiliations

A.N. Nesmeyanov Institute of Organoelement compounds of the Russian Academy of Sciences Vavilova St., 28 Moscow 119991 Russian Federation |

Department of Physics of Polymers and Crystals Faculty of Physics M.V. Lomonosov Moscow State University Leninskie Gory 1 Moscow 119991 Russain Federation |

Inorganic and Analytical Chemistry Department Tver State University Sadovyi per. 35 Tver 170002 Russian Federation |

⁴

Changchun Institute of Applied Chemistry of Chinese Academy of Sciences State Key Laboratory of Polymer Physics and Chemistry Changchun 130022 China |

⁵

Department of Physics Jai Narayan Vyas University Jodhpur Rajasthan 342011 India |

⁶

Department of Physics The LNM Institute for Information Technology Jamdoli Jaipur Rajasthan 302031 India |

Publication type: Journal Article

Publication date: 2022-03-10

Wiley

Journal: Macromolecular Rapid Communications

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Quartile WOS

Impact factor: 4.6

ISSN: 10221336, 15213927

DOI: 10.1002/marc.202200060

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Materials Chemistry

Organic Chemistry

Polymers and Plastics

Abstract

Two D-A copolymers consisted of fused ring pyrrolo-dithieno-quinoxaline acceptor are synthesized with different donor units, i.e., benzodithiophene (BDT) with alkylthienyl (P134) and 2-ethylhexyloxy (P117) side chains. These copolymers are used as donor and a narrow bandgap acceptor Y6 to fabricate bulk heterojunction polymer solar cell devices. Owing to the strong electron-deficient fused ring pyrrolo-bithieno-quinoxaline and weak alkyl thienyl side chains in BDT, the polymer solar cells based on P134:Y6 attained the power conversion efficiency of 15.42%, which is higher than P117:Y6 counterpart (12.14%). The superior value of PCE for P134:Y6 could be associated with more well-adjusted charge transport, weak charge recombination, proficient exciton generation and dissociation into free charge carriers and their subsequent charge collection owing to the dense π-π stacking distance and more considerable crystal coherence length for the P134:Y6 thin films. This investigation confirms the great potential of a strong acceptor-weak donor tactic for developing efficient D-A copolymers consists of quinoxaline acceptor for polymer solar cells. This article is protected by copyright. All rights reserved.

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Polymers	Polymers, 1, 25% Polymers 1 publication, 25%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 25% Journal of Physical Chemistry C 1 publication, 25%
Exploration	Exploration, 1, 25% Exploration 1 publication, 25%
Dyes and Pigments	Dyes and Pigments, 1, 25% Dyes and Pigments 1 publication, 25%
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Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 25% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 25%
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 25% American Chemical Society (ACS) 1 publication, 25%
Wiley	Wiley, 1, 25% Wiley 1 publication, 25%
Elsevier	Elsevier, 1, 25% Elsevier 1 publication, 25%
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Keshtov M. L. et al. Novel Pyrrolo [3,4-b] Dithieno [3, 2-f:2″,3″-h] Quinoxaline-8,10 (9H)-Dione Based Wide Bandgap Conjugated Copolymers for Bulk Heterojunction Polymer Solar Cells // Macromolecular Rapid Communications. 2022. Vol. 43. No. 9. p. 2200060.

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Keshtov M. L., Khokhlov A. R., Godovsky D. Y., Ostapov I. E., Alekseev V. G., Xie Z., Chayal G., Sharma G. D. Novel Pyrrolo [3,4-b] Dithieno [3, 2-f:2″,3″-h] Quinoxaline-8,10 (9H)-Dione Based Wide Bandgap Conjugated Copolymers for Bulk Heterojunction Polymer Solar Cells // Macromolecular Rapid Communications. 2022. Vol. 43. No. 9. p. 2200060.

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RIS Copy

TY - JOUR

DO - 10.1002/marc.202200060

UR - https://doi.org/10.1002%2Fmarc.202200060

TI - Novel Pyrrolo [3,4-b] Dithieno [3, 2-f:2″,3″-h] Quinoxaline-8,10 (9H)-Dione Based Wide Bandgap Conjugated Copolymers for Bulk Heterojunction Polymer Solar Cells

T2 - Macromolecular Rapid Communications

AU - Khokhlov, Alexei R.

AU - Godovsky, Dimitry Y

AU - Alekseev, Vladimir G

AU - Chayal, Giriraj

AU - Keshtov, Mukhamed L

AU - Ostapov, Ilya E

AU - Xie, Zhiyuan

AU - Sharma, Ganesh Datt

PY - 2022

DA - 2022/03/10 00:00:00

PB - Wiley

SP - 2200060

IS - 9

VL - 43

SN - 1022-1336

SN - 1521-3927

ER -

BibTex |

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@article{2022_Keshtov,

author = {Alexei R. Khokhlov and Dimitry Y Godovsky and Vladimir G Alekseev and Giriraj Chayal and Mukhamed L Keshtov and Ilya E Ostapov and Zhiyuan Xie and Ganesh Datt Sharma},

title = {Novel Pyrrolo [3,4-b] Dithieno [3, 2-f:2″,3″-h] Quinoxaline-8,10 (9H)-Dione Based Wide Bandgap Conjugated Copolymers for Bulk Heterojunction Polymer Solar Cells},

journal = {Macromolecular Rapid Communications},

year = {2022},

volume = {43},

publisher = {Wiley},

month = {mar},

url = {https://doi.org/10.1002%2Fmarc.202200060},

number = {9},

pages = {2200060},

doi = {10.1002/marc.202200060}

}

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Keshtov, Mukhamed L., et al. “Novel Pyrrolo [3,4-b] Dithieno [3, 2-f:2″,3″-h] Quinoxaline-8,10 (9H)-Dione Based Wide Bandgap Conjugated Copolymers for Bulk Heterojunction Polymer Solar Cells.” Macromolecular Rapid Communications, vol. 43, no. 9, Mar. 2022, p. 2200060. https://doi.org/10.1002%2Fmarc.202200060.

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Publisher

Wiley

Journal

Macromolecular Rapid Communications

Quartile SCImago

Quartile WOS

Impact factor

4.6

ISSN

10221336 (Print)
15213927 (Electronic)

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