volume 2 issue 2 pages 151-168

Statistics of stiff polymer chains near an adsorbing surface

Publication typeJournal Article
Publication date1993-03-01
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ISSN10185054
General Materials Science
Abstract
The exact solution of the problem of adsorption of a long ideal polymer chain with variable degree of stiffness on a plane surface is presented. It is shown that the adsorption of stiff polymer chains is a second-order phase transition; in the adsorbed state “train” (i.e. adsorbed) sections are relatively longer and loop sections relatively shorter than for flexible chains. This effect is very pronounced: already for moderately stiff chains the number of Kuhn segment lengths in one “train” section at the temperature T = Tcr/2 (Tcr is the critical temperature for adsorption transition) can reach several thousands, and deviation from the surface occurs only in the form of small “hairpins”. The maximum length of the chain, which at the given conditions would flatten completely on the surface, is estimated.
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Khokhlov A. R., Ternovsky F. F., Zheligovskaya E. A. Statistics of stiff polymer chains near an adsorbing surface // Die Makromolekulare Chemie Theory and Simulations. 1993. Vol. 2. No. 2. pp. 151-168.
GOST all authors (up to 50) Copy
Khokhlov A. R., Ternovsky F. F., Zheligovskaya E. A. Statistics of stiff polymer chains near an adsorbing surface // Die Makromolekulare Chemie Theory and Simulations. 1993. Vol. 2. No. 2. pp. 151-168.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/mats.1993.040020201
UR - https://doi.org/10.1002/mats.1993.040020201
TI - Statistics of stiff polymer chains near an adsorbing surface
T2 - Die Makromolekulare Chemie Theory and Simulations
AU - Khokhlov, Alexei R.
AU - Ternovsky, Felix F
AU - Zheligovskaya, Ekaterina A.
PY - 1993
DA - 1993/03/01
PB - Wiley
SP - 151-168
IS - 2
VL - 2
SN - 1018-5054
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{1993_Khokhlov,
author = {Alexei R. Khokhlov and Felix F Ternovsky and Ekaterina A. Zheligovskaya},
title = {Statistics of stiff polymer chains near an adsorbing surface},
journal = {Die Makromolekulare Chemie Theory and Simulations},
year = {1993},
volume = {2},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/mats.1993.040020201},
number = {2},
pages = {151--168},
doi = {10.1002/mats.1993.040020201}
}
MLA
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MLA Copy
Khokhlov, Alexei R., et al. “Statistics of stiff polymer chains near an adsorbing surface.” Die Makromolekulare Chemie Theory and Simulations, vol. 2, no. 2, Mar. 1993, pp. 151-168. https://doi.org/10.1002/mats.1993.040020201.