Journal of Polymer Science, volume 59, issue 24, pages 3150-3160
Living ring‐opening metathesis polymerization of norbornenes bay ‐functionalized perylene diimides
Santhosh Kumar Podiyanachari
1
,
Maciej Barłóg
1
,
Marc Comí
1
,
Salahuddin S Attar
1
,
Saeed Al Meer
2
,
Muhaned Al‐Hashimi
1
,
Hassan S. Bazzi
1, 3
3
Department of Materials Science & Engineering Texas A&M University College Station Texas USA
|
Publication type: Journal Article
Publication date: 2021-10-14
Journal:
Journal of Polymer Science
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.4
ISSN: 00223832, 15426238, 26424150, 26424169
Materials Chemistry
Physical and Theoretical Chemistry
Polymers and Plastics
Abstract
Ring-opening metathesis polymerization (ROMP)-derived poly(oxanorbornene imide)s bearing bay-linked mono-alkoxy-M1 and 1,7-di-alkoxy M2 functionalized perylene diimides (PDIs) were synthesized using Grubb's third (G3) and Hoveyda-Grubbs second generation (HG2) ruthenium-alkylidene metathesis initiators. The mono-alkoxy-derived PDI-based non-ladderphane polymer polyM1 displayed 67% to 77% of the trans olefin content in the polymer chain depending on the initiator used for the polymerization. When using the symmetrical 1,7-di-alkoxy-derived PDI-based polymer polyM2 having the ladderphane type-structure, this displayed a significant amount of cis and trans olefin contents in the polymer chains, irrespective of the type of initiators used for the polymerization. ROMP of both monomers M1 and M2 proceeded in a well-controlled manner with a linear dependence of molecular weight on the monomer/initiator ratio using G3 as initiator. Optical properties of the ladderphane-based polyM2 and non-ladderphane-based polyM1 were characterized in both solution and the film state. X-ray diffraction (XRD) analysis for all the polymers showed significant π-stacking in the thin film state with ordered molecular packing and closer values of d-spacing for both polyM1 and polyM2. Film morphology examined by AFM elucidated homogenous smooth polymer surface for both polymers in general, but with some irregularities observed for polyM1. In addition, CV analysis revealed both polymers could be good candidates as electron-accepting materials, with excellent film-forming ability, and thermal stability.
Top-30
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2 publications, 28.57%
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1 publication, 14.29%
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1 publication, 14.29%
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1 publication, 14.29%
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Citations by publishers
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5 publications, 71.43%
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American Institute of Physics (AIP)
1 publication, 14.29%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 14.29%
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Podiyanachari S. K. et al. Living ring‐opening metathesis polymerization of norbornenes bay ‐functionalized perylene diimides // Journal of Polymer Science. 2021. Vol. 59. No. 24. pp. 3150-3160.
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Podiyanachari S. K., Barłóg M., Comí M., Attar S. S., Al Meer S., Al‐Hashimi M., Bazzi H. S. Living ring‐opening metathesis polymerization of norbornenes bay ‐functionalized perylene diimides // Journal of Polymer Science. 2021. Vol. 59. No. 24. pp. 3150-3160.
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TY - JOUR
DO - 10.1002/pol.20210662
UR - https://doi.org/10.1002/pol.20210662
TI - Living ring‐opening metathesis polymerization of norbornenes bay ‐functionalized perylene diimides
T2 - Journal of Polymer Science
AU - Podiyanachari, Santhosh Kumar
AU - Barłóg, Maciej
AU - Al‐Hashimi, Muhaned
AU - Comí, Marc
AU - Attar, Salahuddin S
AU - Al Meer, Saeed
AU - Bazzi, Hassan S.
PY - 2021
DA - 2021/10/14 00:00:00
PB - Wiley
SP - 3150-3160
IS - 24
VL - 59
SN - 0022-3832
SN - 1542-6238
SN - 2642-4150
SN - 2642-4169
ER -
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@article{2021_Podiyanachari,
author = {Santhosh Kumar Podiyanachari and Maciej Barłóg and Muhaned Al‐Hashimi and Marc Comí and Salahuddin S Attar and Saeed Al Meer and Hassan S. Bazzi},
title = {Living ring‐opening metathesis polymerization of norbornenes bay ‐functionalized perylene diimides},
journal = {Journal of Polymer Science},
year = {2021},
volume = {59},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/pol.20210662},
number = {24},
pages = {3150--3160},
doi = {10.1002/pol.20210662}
}
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Podiyanachari, Santhosh Kumar, et al. “Living ring‐opening metathesis polymerization of norbornenes bay ‐functionalized perylene diimides.” Journal of Polymer Science, vol. 59, no. 24, Oct. 2021, pp. 3150-3160. https://doi.org/10.1002/pol.20210662.