Improved In Vitro Antimycobacterial Activity of Trinuclear Complexes Cobalt(II,III) and Iron(III) with 2-Furoic Acid against Mycolicibacterium smegmatis
Irina A Lutsenko
1
,
Petr V Primakov
2
,
Olga B Bekker
3
,
Oleg A Levitskiy
4
,
Yurii V Maksimov
5
,
A.V Sidorov
1
,
В. Н. Даниленко
3
,
Igor L. Eremenko
1, 2
Тип публикации: Journal Article
Дата публикации: 2020-10-09
scimago Q3
wos Q3
БС2
SJR: 0.366
CiteScore: 3.0
Impact factor: 2.0
ISSN: 23656549
General Chemistry
Краткое описание
The reaction of cobalt(II) and iron(III) pivalates with anions of 2‐furancarboxylic acid (pyromucic acid, Hfur) yielded trinuclear homometallic complexes with linear ([Co3(fur)6(phen)2] (1, phen=1,10‐phenanthroline)) and triangular ([Co3O(fur)6(H2O)3] (3), [Fe3O(fur)6(THF)3] ⋅ 3THF (4)) structures of the metal moiety. The hexanuclear mixed carboxylate cobalt complex [Co6(piv)8(Hpiv)4(fur)2(OH)2] (2, piv−=(CH3)3COO−) was isolated as an intermediate in the synthesis of 3. According to CVA data, complex 3 contains bivalent and trivalent cobalt ions. According to Mossbauer spectroscopy data, all the iron(III) atoms in 4, which is an isostructural analogue of 3, are solely in the high‐spin state. The antibacterial activity of compounds 1–4, K(fur) (5) and Na(fur) (6) was determined in vitro against a non‐pathogenic Mycolicibacterium smegmatis strain. The results of in vitro biological tests against Mycolicibacterium smegmatis showed a high bioactivity of complexes 1 and 4.
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Lutsenko I. A. et al. Improved In Vitro Antimycobacterial Activity of Trinuclear Complexes Cobalt(II,III) and Iron(III) with 2-Furoic Acid against Mycolicibacterium smegmatis // ChemistrySelect. 2020. Vol. 5. No. 38. pp. 11837-11842.
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Lutsenko I. A., Yambulatov D. S., Kiskin M. A., Nelyubina Y. V., Primakov P. V., Bekker O. B., Levitskiy O. A., Magdesieva T. V., Imshennik V. K., Maksimov Y. V., Sidorov A., Даниленко В. Н., Eremenko I. L. Improved In Vitro Antimycobacterial Activity of Trinuclear Complexes Cobalt(II,III) and Iron(III) with 2-Furoic Acid against Mycolicibacterium smegmatis // ChemistrySelect. 2020. Vol. 5. No. 38. pp. 11837-11842.
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TY - JOUR
DO - 10.1002/slct.202003101
UR - https://doi.org/10.1002/slct.202003101
TI - Improved In Vitro Antimycobacterial Activity of Trinuclear Complexes Cobalt(II,III) and Iron(III) with 2-Furoic Acid against Mycolicibacterium smegmatis
T2 - ChemistrySelect
AU - Lutsenko, Irina A
AU - Yambulatov, Dmitriy S
AU - Kiskin, Mikhail A.
AU - Nelyubina, Yulia V.
AU - Primakov, Petr V
AU - Bekker, Olga B
AU - Levitskiy, Oleg A
AU - Magdesieva, Tatiana V.
AU - Imshennik, Vladimir K
AU - Maksimov, Yurii V
AU - Sidorov, A.V
AU - Даниленко, В. Н.
AU - Eremenko, Igor L.
PY - 2020
DA - 2020/10/09
PB - Wiley
SP - 11837-11842
IS - 38
VL - 5
SN - 2365-6549
ER -
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@article{2020_Lutsenko,
author = {Irina A Lutsenko and Dmitriy S Yambulatov and Mikhail A. Kiskin and Yulia V. Nelyubina and Petr V Primakov and Olga B Bekker and Oleg A Levitskiy and Tatiana V. Magdesieva and Vladimir K Imshennik and Yurii V Maksimov and A.V Sidorov and В. Н. Даниленко and Igor L. Eremenko},
title = {Improved In Vitro Antimycobacterial Activity of Trinuclear Complexes Cobalt(II,III) and Iron(III) with 2-Furoic Acid against Mycolicibacterium smegmatis},
journal = {ChemistrySelect},
year = {2020},
volume = {5},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/slct.202003101},
number = {38},
pages = {11837--11842},
doi = {10.1002/slct.202003101}
}
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Lutsenko, Irina A., et al. “Improved In Vitro Antimycobacterial Activity of Trinuclear Complexes Cobalt(II,III) and Iron(III) with 2-Furoic Acid against Mycolicibacterium smegmatis.” ChemistrySelect, vol. 5, no. 38, Oct. 2020, pp. 11837-11842. https://doi.org/10.1002/slct.202003101.