Open Access
Small, volume 16, issue 47, pages 2004782
Nano-Thermodynamics of Chemically Induced Graphene–Diamond Transformation
Publication type: Journal Article
Publication date: 2020-10-26
General Chemistry
Biotechnology
General Materials Science
Biomaterials
Abstract
Nearly 2D diamond, or diamane, is coveted as an ultrathin sp3 -carbon film with unique mechanics and electro-optics. The very thinness (≈h) makes it possible for the surface chemistry, for example, adsorbed atoms, to shift the bulk phase thermodynamics in favor of diamond, from multilayer graphene. Thermodynamic theory coupled with atomistic first principles computations predicts not only the reduction of required pressure (p/p∞ > 1 - h0 /h) but also the nucleation barriers, definitive for the kinetic feasibility of diamane formation. Moreover, the optimal adsorbent chair-pattern on a bilayer graphene results in a cubic diamond lattice, while for thicker precursors the adsorbent boat-structure tends to produce hexagonal diamond (lonsdaleite), if graphene is in AA' stacking to start with. As adsorbents, H and F are conducive to diamond formation, while Cl appears sterically hindered.
Citations by journals
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3
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Journal of Physical Chemistry Letters
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Journal of Physical Chemistry Letters
3 publications, 12%
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Nanomaterials
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Nanomaterials
3 publications, 12%
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Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics
3 publications, 12%
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Nano Letters
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Nano Letters
1 publication, 4%
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Materials
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Materials
1 publication, 4%
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C – Journal of Carbon Research
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C – Journal of Carbon Research
1 publication, 4%
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Nature Reviews Materials
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Nature Reviews Materials
1 publication, 4%
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ACS applied materials & interfaces
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ACS applied materials & interfaces
1 publication, 4%
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Diamond and Related Materials
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Diamond and Related Materials
1 publication, 4%
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Applied Surface Science
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Applied Surface Science
1 publication, 4%
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Carbon
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Carbon
1 publication, 4%
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Advanced Theory and Simulations
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Advanced Theory and Simulations
1 publication, 4%
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Advanced Science
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Advanced Science
1 publication, 4%
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ACS Sustainable Chemistry and Engineering
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ACS Sustainable Chemistry and Engineering
1 publication, 4%
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Fullerenes Nanotubes and Carbon Nanostructures
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Fullerenes Nanotubes and Carbon Nanostructures
1 publication, 4%
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Small
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Small
1 publication, 4%
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Journal of Physical Chemistry C
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Journal of Physical Chemistry C
1 publication, 4%
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ACS Applied Electronic Materials
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ACS Applied Electronic Materials
1 publication, 4%
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Advanced Functional Materials
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Advanced Functional Materials
1 publication, 4%
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3
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Citations by publishers
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1
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8
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American Chemical Society (ACS)
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American Chemical Society (ACS)
8 publications, 32%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
5 publications, 20%
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Wiley
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Wiley
4 publications, 16%
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Elsevier
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Elsevier
3 publications, 12%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
3 publications, 12%
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Springer Nature
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Springer Nature
1 publication, 4%
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Taylor & Francis
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Taylor & Francis
1 publication, 4%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Erohin S. V. et al. Nano-Thermodynamics of Chemically Induced Graphene–Diamond Transformation // Small. 2020. Vol. 16. No. 47. p. 2004782.
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Erohin S. V., Ruan Q., Sorokin P. B., Yakobson B. I. Nano-Thermodynamics of Chemically Induced Graphene–Diamond Transformation // Small. 2020. Vol. 16. No. 47. p. 2004782.
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TY - JOUR
DO - 10.1002/smll.202004782
UR - https://doi.org/10.1002%2Fsmll.202004782
TI - Nano-Thermodynamics of Chemically Induced Graphene–Diamond Transformation
T2 - Small
AU - Ruan, Qiyuan
AU - Yakobson, Boris I.
AU - Erohin, Sergey V
AU - Sorokin, Pavel B.
PY - 2020
DA - 2020/10/26 00:00:00
PB - Wiley
SP - 2004782
IS - 47
VL - 16
SN - 1613-6810
SN - 1613-6829
ER -
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@article{2020_Erohin,
author = {Qiyuan Ruan and Boris I. Yakobson and Sergey V Erohin and Pavel B. Sorokin},
title = {Nano-Thermodynamics of Chemically Induced Graphene–Diamond Transformation},
journal = {Small},
year = {2020},
volume = {16},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002%2Fsmll.202004782},
number = {47},
pages = {2004782},
doi = {10.1002/smll.202004782}
}
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Erohin, Sergey V., et al. “Nano-Thermodynamics of Chemically Induced Graphene–Diamond Transformation.” Small, vol. 16, no. 47, Oct. 2020, p. 2004782. https://doi.org/10.1002%2Fsmll.202004782.