Hydrogen bonds and protonation of carbonyl-containing polynuclear rhodium complexes
Publication type: Journal Article
Publication date: 1995-02-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
According to IR spectroscopy data, the interaction of bi-, tri-, and tetranuclear cyclopentadienylcarbonyl rhodium complexes with rather weak protic acids (phenols, fluoroalcohols) in low-polarity media results in the formation of hydrogen bonds of the OH...O=C type with bridged carbonyl groups. According to1H NMR data, protonation of these complexes with strong acids (CF3COOH and HBF4) occurs at the the Rh-Rh bond to give the symmetrical $$\begin{array}{*{20}c} {} & {} & H & {} \\ {} & / & {} & \backslash \\ {Rh} & - & - & - \\ {} & {} & {} & {} \\ \end{array} \begin{array}{*{20}c} {} \\ { Rh} \\ \end{array} $$ bridge.
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Krylov A. et al. Hydrogen bonds and protonation of carbonyl-containing polynuclear rhodium complexes // Russian Chemical Bulletin. 1995. Vol. 44. No. 2. pp. 378-379.
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Krylov A., Shubina E. S., Muratov D. V., Vorontsov E., Epshtein L. M. Hydrogen bonds and protonation of carbonyl-containing polynuclear rhodium complexes // Russian Chemical Bulletin. 1995. Vol. 44. No. 2. pp. 378-379.
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TY - JOUR
DO - 10.1007/BF00702158
UR - https://doi.org/10.1007/BF00702158
TI - Hydrogen bonds and protonation of carbonyl-containing polynuclear rhodium complexes
T2 - Russian Chemical Bulletin
AU - Krylov, A.N.
AU - Shubina, E. S.
AU - Muratov, D V
AU - Vorontsov, E.V.
AU - Epshtein, L M
PY - 1995
DA - 1995/02/01
PB - Springer Nature
SP - 378-379
IS - 2
VL - 44
SN - 1066-5285
SN - 1573-9171
ER -
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@article{1995_Krylov,
author = {A.N. Krylov and E. S. Shubina and D V Muratov and E.V. Vorontsov and L M Epshtein},
title = {Hydrogen bonds and protonation of carbonyl-containing polynuclear rhodium complexes},
journal = {Russian Chemical Bulletin},
year = {1995},
volume = {44},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/BF00702158},
number = {2},
pages = {378--379},
doi = {10.1007/BF00702158}
}
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MLA
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Krylov, A.N., et al. “Hydrogen bonds and protonation of carbonyl-containing polynuclear rhodium complexes.” Russian Chemical Bulletin, vol. 44, no. 2, Feb. 1995, pp. 378-379. https://doi.org/10.1007/BF00702158.
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