том 49 издание 1 страницы 150-153

Metallation of the methyl group in o-nitrosotoluene: Synthesis and the molecular structure of the binuclear complex [o-(NO)(CH2)C6H4]2Pd2 (μ-OOCCF3)2

Тип публикацииJournal Article
Дата публикации1990-01-01
scimago Q3
БС2
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Краткое описание
The reaction of the tetranuclear cluster Pd4(CO)4(OOCCF3)4 witho-nitrosotoluene afforded the Pd11-containing complex [o-(NO)(CH2)C6H4]2Pd2(μ-OOCCF3)2. The elimination of CO2 and the formation of organic products of transformation of tolylnitrene species (azotoluene, ditolylamine, and tolylisocyanate) were observed in the course of the reaction. The title complex was characterized by IR and1H NMR spectroscopy. Its structure was established by X-ray diffraction analysis. It was suggested that the reaction proceeds through intermediate formation of nitrene complexes.
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Inorganica Chimica Acta
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Stromnova T. A. et al. Metallation of the methyl group in o-nitrosotoluene: Synthesis and the molecular structure of the binuclear complex [o-(NO)(CH2)C6H4]2Pd2 (μ-OOCCF3)2 // Russian Chemical Bulletin. 1990. Vol. 49. No. 1. pp. 150-153.
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Stromnova T. A., Orlova S. T., Kazyulkin D. N., Stolyarov I. P., Eremenko I. L. Metallation of the methyl group in o-nitrosotoluene: Synthesis and the molecular structure of the binuclear complex [o-(NO)(CH2)C6H4]2Pd2 (μ-OOCCF3)2 // Russian Chemical Bulletin. 1990. Vol. 49. No. 1. pp. 150-153.
RIS |
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TY - JOUR
DO - 10.1007/BF02499082
UR - https://doi.org/10.1007/BF02499082
TI - Metallation of the methyl group in o-nitrosotoluene: Synthesis and the molecular structure of the binuclear complex [o-(NO)(CH2)C6H4]2Pd2 (μ-OOCCF3)2
T2 - Russian Chemical Bulletin
AU - Stromnova, T. A.
AU - Orlova, S T
AU - Kazyulkin, D N
AU - Stolyarov, I P
AU - Eremenko, I. L.
PY - 1990
DA - 1990/01/01
PB - Springer Nature
SP - 150-153
IS - 1
VL - 49
SN - 1066-5285
SN - 1573-9171
ER -
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@article{1990_Stromnova,
author = {T. A. Stromnova and S T Orlova and D N Kazyulkin and I P Stolyarov and I. L. Eremenko},
title = {Metallation of the methyl group in o-nitrosotoluene: Synthesis and the molecular structure of the binuclear complex [o-(NO)(CH2)C6H4]2Pd2 (μ-OOCCF3)2},
journal = {Russian Chemical Bulletin},
year = {1990},
volume = {49},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/BF02499082},
number = {1},
pages = {150--153},
doi = {10.1007/BF02499082}
}
MLA
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Stromnova, T. A., et al. “Metallation of the methyl group in o-nitrosotoluene: Synthesis and the molecular structure of the binuclear complex [o-(NO)(CH2)C6H4]2Pd2 (μ-OOCCF3)2.” Russian Chemical Bulletin, vol. 49, no. 1, Jan. 1990, pp. 150-153. https://doi.org/10.1007/BF02499082.