Colloid and Polymer Science

, том 284 , издание 2 , страницы 117-123

Two-dimensional classification of amphiphilic monomers based on interfacial and partitioning properties. 1. Monomers of synthetic water-soluble polymers

Тип публикации: Journal Article

Дата публикации: 2005-07-28

Springer Nature

Colloid and Polymer Science

scimago Q2

wos Q3

БС2

SJR: 0.431

CiteScore: 4.5

Impact factor: 2.3

ISSN: 0303402X, 14351536

DOI: 10.1007/s00396-005-1342-1

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Materials Chemistry

Physical and Theoretical Chemistry

Colloid and Surface Chemistry

Polymers and Plastics

Краткое описание

A classification of amphiphilic monomers based on the interfacial and partitioning properties has been proposed. Monomers partitioned at equilibrium between two immiscible phases were ascribed with a pair of parameters: standard free energy of adsorption at the interface and standard free energy of partition between the two phases. These two parameters are represented in a form of two-dimensional diagram (both of them being normalized by kT factor). Comparison of the parameters in question gives information on energetic preferences of the molecules to be located at the interface or in the bulk phases. Four monomers of synthetic water-soluble polymers, namely, N-isopropylacrylamide, 1-vinylimidazole, N-vinylpyrrolidone and N-vinylcaprolactam have been classified according to the above method at various temperatures. The possibility to extend the classification to arbitrary chemicals is discussed.

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д.ф.-м.н., проф.

121 публикация, 2 523 цитирования, 59 рецензий

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Институт элементоорганических соединений им. А.Н. Несмеянова РАН

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Высокомолекулярные соединения

Компьютерное моделирование

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Хохлов Алексей

д.ф.-м.н., проф., академик, Российская академия наук

822 публикации, 21 447 цитирований

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Московский государственный университет имени М.В. Ломоносова

Институт элементоорганических соединений им. А.Н. Несмеянова РАН

Области научных интересов

Наука о полимерах

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1 цитирование

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Московский государственный университет имени М.В. Ломоносова

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Okhapkin I. M. et al. Two-dimensional classification of amphiphilic monomers based on interfacial and partitioning properties. 1. Monomers of synthetic water-soluble polymers // Colloid and Polymer Science. 2005. Vol. 284. No. 2. pp. 117-123.

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Okhapkin I. M., Makhaeva E. E., Khokhlov A. R. Two-dimensional classification of amphiphilic monomers based on interfacial and partitioning properties. 1. Monomers of synthetic water-soluble polymers // Colloid and Polymer Science. 2005. Vol. 284. No. 2. pp. 117-123.

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TY - JOUR

DO - 10.1007/s00396-005-1342-1

UR - https://doi.org/10.1007/s00396-005-1342-1

TI - Two-dimensional classification of amphiphilic monomers based on interfacial and partitioning properties. 1. Monomers of synthetic water-soluble polymers

T2 - Colloid and Polymer Science

AU - Okhapkin, Ivan M

AU - Makhaeva, Elena E.

AU - Khokhlov, Alexei R.

PY - 2005

DA - 2005/07/28

PB - Springer Nature

SP - 117-123

IS - 2

VL - 284

SN - 0303-402X

SN - 1435-1536

ER -

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@article{2005_Okhapkin,

author = {Ivan M Okhapkin and Elena E. Makhaeva and Alexei R. Khokhlov},

title = {Two-dimensional classification of amphiphilic monomers based on interfacial and partitioning properties. 1. Monomers of synthetic water-soluble polymers},

journal = {Colloid and Polymer Science},

year = {2005},

volume = {284},

publisher = {Springer Nature},

month = {jul},

url = {https://doi.org/10.1007/s00396-005-1342-1},

number = {2},

pages = {117--123},

doi = {10.1007/s00396-005-1342-1}

}

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Okhapkin, Ivan M., et al. “Two-dimensional classification of amphiphilic monomers based on interfacial and partitioning properties. 1. Monomers of synthetic water-soluble polymers.” Colloid and Polymer Science, vol. 284, no. 2, Jul. 2005, pp. 117-123. https://doi.org/10.1007/s00396-005-1342-1.