Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review
Mikhail M Levitsky
1
,
Yan V. Zubavichus
2
,
Alexander A. Korlyukov
1, 3
,
Victor N. Khrustalev
4
,
Elena S Shubina
1
,
Publication type: Journal Article
Publication date: 2019-05-04
scimago Q2
wos Q1
SJR: 0.515
CiteScore: 6.7
Impact factor: 3.6
ISSN: 10407278, 15728862
General Chemistry
Biochemistry
Condensed Matter Physics
General Materials Science
Abstract
In the present paper, a rapidly developing field of polynuclear cage metallasilsesquioxanes and metallagermsesquioxanes chemistry is surveyed. Deliberate synthesis techniques aimed at the cages of specific nuclearity are described with the emphasis placed onto analysis of similarities and differences between silicon- and germanium-based substances. General approaches towards design of polymeric supramolecular assemblies based on cage metallasilsesquioxanes and metallagermsesquioxanes are outlined and illustrated with appropriate examples. Striking catalytic properties of the title compounds in homogeneous oxidation reactions are noted as one of their prospective application field.
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Metrics
40
Total citations:
40
Citations from 2024:
8
(20%)
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MLA
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GOST
Copy
Levitsky M. M. et al. Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review // Journal of Cluster Science. 2019. Vol. 30. No. 5. pp. 1283-1316.
GOST all authors (up to 50)
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Levitsky M. M., Zubavichus Y. V., Korlyukov A. A., Khrustalev V. N., Shubina E. S., Bilyachenko A. N. Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review // Journal of Cluster Science. 2019. Vol. 30. No. 5. pp. 1283-1316.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s10876-019-01567-y
UR - https://doi.org/10.1007/s10876-019-01567-y
TI - Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review
T2 - Journal of Cluster Science
AU - Levitsky, Mikhail M
AU - Zubavichus, Yan V.
AU - Korlyukov, Alexander A.
AU - Khrustalev, Victor N.
AU - Shubina, Elena S
AU - Bilyachenko, Alexey N.
PY - 2019
DA - 2019/05/04
PB - Springer Nature
SP - 1283-1316
IS - 5
VL - 30
SN - 1040-7278
SN - 1572-8862
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Levitsky,
author = {Mikhail M Levitsky and Yan V. Zubavichus and Alexander A. Korlyukov and Victor N. Khrustalev and Elena S Shubina and Alexey N. Bilyachenko},
title = {Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review},
journal = {Journal of Cluster Science},
year = {2019},
volume = {30},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1007/s10876-019-01567-y},
number = {5},
pages = {1283--1316},
doi = {10.1007/s10876-019-01567-y}
}
Cite this
MLA
Copy
Levitsky, Mikhail M., et al. “Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review.” Journal of Cluster Science, vol. 30, no. 5, May. 2019, pp. 1283-1316. https://doi.org/10.1007/s10876-019-01567-y.
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