Influence of the nature of organic ligands on the character of thermal decomposition products of CoII and NiII pivalate complexes with amino derivatives of pyridine
Publication type: Journal Article
Publication date: 2010-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The thermal stability and the solid-state thermal decomposition of the known mononuclear cobalt(II) and nickel(II) complexes [H2N(C5H3N)N(H)C(Me)=NH]M(OOCBut)2, [(NH2)2C6H2Me2]3M(OOCBut)2 and the new compounds L2M(OOCBut)2 (L = = (2-NH2)C5H3N, (2-NH2)(6-Me)C5H3N), and [(2,6-NH2)2C5H3N]2Ni(OOCBut)2 were studied by differential scanning calorimetry and thermogravimetric analysis. Efficient methods were developed for the synthesis of these complexes. The mononuclear complexes are thermally quite stable. The thermal stability of the complexes depends on the nature of the ligand and decreases in the series (2,6-NH2)2C5H3N > H2N(C5H3N)NHC(Me)=NH > (NH2)2C6H2Me2 > (2-NH2)C5H3N > (2-NH2)(6-Me)C5H3N. The nickel(II) complexes are thermally more stable than the related cobalt(II) complexes. The thermolysis (<500 °C) of Co and Ni pivalates is a destructive process. The phase composition of the decomposition products is determined by the nature of metal and coordinated ligands.
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Fomina I. et al. Influence of the nature of organic ligands on the character of thermal decomposition products of CoII and NiII pivalate complexes with amino derivatives of pyridine // Russian Chemical Bulletin. 2010. Vol. 59. No. 6. pp. 1175-1185.
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Fomina I., Dobrokhotova Z. V., Aleksandrov G., Bogomyakov A. S., Novotortsev V. M., Eremenko I. L. Influence of the nature of organic ligands on the character of thermal decomposition products of CoII and NiII pivalate complexes with amino derivatives of pyridine // Russian Chemical Bulletin. 2010. Vol. 59. No. 6. pp. 1175-1185.
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TY - JOUR
DO - 10.1007/s11172-010-0220-2
UR - https://doi.org/10.1007/s11172-010-0220-2
TI - Influence of the nature of organic ligands on the character of thermal decomposition products of CoII and NiII pivalate complexes with amino derivatives of pyridine
T2 - Russian Chemical Bulletin
AU - Fomina, I.G.
AU - Dobrokhotova, Zh V
AU - Aleksandrov, G.G.
AU - Bogomyakov, A S
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2010
DA - 2010/06/01
PB - Springer Nature
SP - 1175-1185
IS - 6
VL - 59
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2010_Fomina,
author = {I.G. Fomina and Zh V Dobrokhotova and G.G. Aleksandrov and A S Bogomyakov and V. M. Novotortsev and I. L. Eremenko},
title = {Influence of the nature of organic ligands on the character of thermal decomposition products of CoII and NiII pivalate complexes with amino derivatives of pyridine},
journal = {Russian Chemical Bulletin},
year = {2010},
volume = {59},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11172-010-0220-2},
number = {6},
pages = {1175--1185},
doi = {10.1007/s11172-010-0220-2}
}
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Fomina, I.G., et al. “Influence of the nature of organic ligands on the character of thermal decomposition products of CoII and NiII pivalate complexes with amino derivatives of pyridine.” Russian Chemical Bulletin, vol. 59, no. 6, Jun. 2010, pp. 1175-1185. https://doi.org/10.1007/s11172-010-0220-2.