Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework — the iron(iii) complex with benzene-1,3,5-tricarboxylate
S.A. Sotnik
1
,
S V Kolotilov
1
,
M. A. Kiskin
2
,
Zh V Dobrokhotova
2
,
K S Gavrilenko
3
,
V. M. Novotortsev
2
,
I. L. Eremenko
2
,
V.K Imshennik
4
,
Yu. V. Maksimov
4
,
V V Pavlishchuk
1
1
L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
|
3
Chembio Center, National Taras Shevchenko University of Kyiv, Kiev, Ukraine
|
Тип публикации: Journal Article
Дата публикации: 2014-04-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
A new iron(iii) coordination compound with the benzene-1,3,5-tricarboxylate anion of the composition [Fe iii 2(OH)0.3(H2O)1.7(btc)4/3]Cl1.7·2.8DMF·1.9H2O (1) was synthesized. Its crystal structure was determined, and the Mössbauer spectra were analyzed. The adsorption of salicylaldehyde and nitromethane by compound 1 was studied. The adsorption kinetics of salicylaldehyde is described by the pseudo-second order equation. The diffusion of this aldehyde in particles of compound 1 is, most probably, the rate-limiting step in the Henry reaction.
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Sotnik S. et al. Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework — the iron(iii) complex with benzene-1,3,5-tricarboxylate // Russian Chemical Bulletin. 2014. Vol. 63. No. 4. pp. 862-869.
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Sotnik S., Kolotilov S. V., Kiskin M. A., Dobrokhotova Z. V., Gavrilenko K. S., Novotortsev V. M., Eremenko I. L., Imshennik V., Maksimov Y. V., Pavlishchuk V. V. Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework — the iron(iii) complex with benzene-1,3,5-tricarboxylate // Russian Chemical Bulletin. 2014. Vol. 63. No. 4. pp. 862-869.
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TY - JOUR
DO - 10.1007/s11172-014-0522-x
UR - https://doi.org/10.1007/s11172-014-0522-x
TI - Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework — the iron(iii) complex with benzene-1,3,5-tricarboxylate
T2 - Russian Chemical Bulletin
AU - Sotnik, S.A.
AU - Kolotilov, S V
AU - Kiskin, M. A.
AU - Dobrokhotova, Zh V
AU - Gavrilenko, K S
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
AU - Imshennik, V.K
AU - Maksimov, Yu. V.
AU - Pavlishchuk, V V
PY - 2014
DA - 2014/04/01
PB - Springer Nature
SP - 862-869
IS - 4
VL - 63
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2014_Sotnik,
author = {S.A. Sotnik and S V Kolotilov and M. A. Kiskin and Zh V Dobrokhotova and K S Gavrilenko and V. M. Novotortsev and I. L. Eremenko and V.K Imshennik and Yu. V. Maksimov and V V Pavlishchuk},
title = {Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework — the iron(iii) complex with benzene-1,3,5-tricarboxylate},
journal = {Russian Chemical Bulletin},
year = {2014},
volume = {63},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/s11172-014-0522-x},
number = {4},
pages = {862--869},
doi = {10.1007/s11172-014-0522-x}
}
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Sotnik, S.A., et al. “Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework — the iron(iii) complex with benzene-1,3,5-tricarboxylate.” Russian Chemical Bulletin, vol. 63, no. 4, Apr. 2014, pp. 862-869. https://doi.org/10.1007/s11172-014-0522-x.