(Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding
Publication type: Journal Article
Publication date: 2017-02-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A reaction of iodide [(η5-indenyl)IrI2]n (1) with thallium dicarbollide Tl[Tl(η-7,8-C2B9H11)] leads to (indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11) (2) in 32% yield. The X-ray diffraction study showed that in the structure of 2, the five-membered rings C5 and C2B3 have a cisoid conformation, in which the bridgehead carbon atoms of the indenyl ligand are arranged opposite to the carborane cage carbon atoms. The DFT calculations showed that the Ir—indenyl bond in compound 2 is weaker than the Ir—Cp bond in the complex (η-7,8-C2B9H11)IrCp.
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Loginov D. A. et al. (Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding // Russian Chemical Bulletin. 2017. Vol. 66. No. 2. pp. 346-349.
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Loginov D. A., Idrisov V. O., Nelyubina Yu. V., Laskova Yu. N., Kudinov A. R. (Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding // Russian Chemical Bulletin. 2017. Vol. 66. No. 2. pp. 346-349.
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TY - JOUR
DO - 10.1007/s11172-017-1738-3
UR - http://link.springer.com/10.1007/s11172-017-1738-3
TI - (Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding
T2 - Russian Chemical Bulletin
AU - Loginov, D A
AU - Idrisov, V O
AU - Nelyubina, Yu V
AU - Laskova, Yu N
AU - Kudinov, A. R.
PY - 2017
DA - 2017/02/01
PB - Springer Nature
SP - 346-349
IS - 2
VL - 66
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2017_Loginov,
author = {D A Loginov and V O Idrisov and Yu V Nelyubina and Yu N Laskova and A. R. Kudinov},
title = {(Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding},
journal = {Russian Chemical Bulletin},
year = {2017},
volume = {66},
publisher = {Springer Nature},
month = {feb},
url = {http://link.springer.com/10.1007/s11172-017-1738-3},
number = {2},
pages = {346--349},
doi = {10.1007/s11172-017-1738-3}
}
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MLA
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Loginov, D. A., et al. “(Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding.” Russian Chemical Bulletin, vol. 66, no. 2, Feb. 2017, pp. 346-349. http://link.springer.com/10.1007/s11172-017-1738-3.
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