том 66 издание 2 страницы 346-349

(Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding

Тип публикацииJournal Article
Дата публикации2017-02-01
scimago Q3
БС2
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Краткое описание
A reaction of iodide [(η5-indenyl)IrI2]n (1) with thallium dicarbollide Tl[Tl(η-7,8-C2B9H11)] leads to (indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11) (2) in 32% yield. The X-ray diffraction study showed that in the structure of 2, the five-membered rings C5 and C2B3 have a cisoid conformation, in which the bridgehead carbon atoms of the indenyl ligand are arranged opposite to the carborane cage carbon atoms. The DFT calculations showed that the Ir—indenyl bond in compound 2 is weaker than the Ir—Cp bond in the complex (η-7,8-C2B9H11)IrCp.
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Journal of Organometallic Chemistry
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Russian Chemical Bulletin
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ГОСТ |
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Loginov D. A. et al. (Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding // Russian Chemical Bulletin. 2017. Vol. 66. No. 2. pp. 346-349.
ГОСТ со всеми авторами (до 50) Скопировать
Loginov D. A., Idrisov V. O., Nelyubina Yu. V., Laskova Yu. N., Kudinov A. R. (Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding // Russian Chemical Bulletin. 2017. Vol. 66. No. 2. pp. 346-349.
RIS |
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TY - JOUR
DO - 10.1007/s11172-017-1738-3
UR - http://link.springer.com/10.1007/s11172-017-1738-3
TI - (Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding
T2 - Russian Chemical Bulletin
AU - Loginov, D A
AU - Idrisov, V O
AU - Nelyubina, Yu V
AU - Laskova, Yu N
AU - Kudinov, A. R.
PY - 2017
DA - 2017/02/01
PB - Springer Nature
SP - 346-349
IS - 2
VL - 66
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2017_Loginov,
author = {D A Loginov and V O Idrisov and Yu V Nelyubina and Yu N Laskova and A. R. Kudinov},
title = {(Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding},
journal = {Russian Chemical Bulletin},
year = {2017},
volume = {66},
publisher = {Springer Nature},
month = {feb},
url = {http://link.springer.com/10.1007/s11172-017-1738-3},
number = {2},
pages = {346--349},
doi = {10.1007/s11172-017-1738-3}
}
MLA
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Loginov, D. A., et al. “(Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding.” Russian Chemical Bulletin, vol. 66, no. 2, Feb. 2017, pp. 346-349. http://link.springer.com/10.1007/s11172-017-1738-3.