Science China Chemistry

, volume 62 , issue 5 , pages 571-582

Rare-earth metal catalysts for alkene hydrosilylation

Deshuai Liu ¹

Boyu Liu ¹

Zexiong Pan ¹

Jianfeng Li ¹

Chunming Cui ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

State Key Laboratory of Elemento-Organic Chemistry and College of Chemistry, Nankai University, Tianjin, China |

Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, China |

Publication type: Journal Article

Publication date: 2019-02-22

Springer Nature

Science China Chemistry

scimago Q1

wos Q1

SJR: 2.377

CiteScore: 13.8

Impact factor: 9.7

ISSN: 16747291, 18691870

DOI: 10.1007/s11426-018-9403-7

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General Chemistry

Abstract

Rare-earth metal catalyzed hydrosilylation of alkenes has emerged as a powerful and selective strategy for the synthesis of organosilanes. This transformation can offer distinctive catalytic sequences and reaction patterns from other catalysts because of the high electropositivity and lack of oxidative-addition process of rare-earth metal. This review summarizes the rare-earth metal catalysts for hydrosilylation of alkene according to the type of ligands. The synthesis and structure of rare-earth metal catalysts, the substrate scope as well as some preliminary structure-activity relationship and mechanism are discussed.

Found

2 citations

Lyubov Dmitry

🥼

PhD in Chemistry

74 publications, 2 100 citations

h-index: 28

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

2 citations

Cherkasov Anton

245 publications, 3 701 citations

h-index: 31

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Research interests

Coordination Chemistry

1 citation

Nelyubina Yulia

🤝

DSc in Chemistry

507 publications, 7 665 citations, 1 review

h-index: 38

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Moscow Institute of Physics and Technology

Metal-organic frameworks

Quantum technologies

Sensors

1 citation

Goncharova Irina

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PhD in Chemistry

18 publications, 197 citations

h-index: 8

A.V. Topchiev Institute of Petrochemical Synthesis RAS

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Catalysis

Chemistry of organoelement compounds

Organic synthesis

Organometallic Chemistry

Polymer Chemistry

Selective liquid phase oxidation

1 citation

Obaedkov Anatoliy

PhD in Chemistry

56 publications, 469 citations

h-index: 11

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

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GOST |

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GOST Copy

Liu D. et al. Rare-earth metal catalysts for alkene hydrosilylation // Science China Chemistry. 2019. Vol. 62. No. 5. pp. 571-582.

GOST all authors (up to 50) Copy

Liu D., Liu B., Pan Z., Li J., Cui C. Rare-earth metal catalysts for alkene hydrosilylation // Science China Chemistry. 2019. Vol. 62. No. 5. pp. 571-582.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1007/s11426-018-9403-7

UR - https://doi.org/10.1007/s11426-018-9403-7

TI - Rare-earth metal catalysts for alkene hydrosilylation

T2 - Science China Chemistry

AU - Liu, Deshuai

AU - Liu, Boyu

AU - Pan, Zexiong

AU - Li, Jianfeng

AU - Cui, Chunming

PY - 2019

DA - 2019/02/22

PB - Springer Nature

SP - 571-582

IS - 5

VL - 62

SN - 1674-7291

SN - 1869-1870

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Liu,

author = {Deshuai Liu and Boyu Liu and Zexiong Pan and Jianfeng Li and Chunming Cui},

title = {Rare-earth metal catalysts for alkene hydrosilylation},

journal = {Science China Chemistry},

year = {2019},

volume = {62},

publisher = {Springer Nature},

month = {feb},

url = {https://doi.org/10.1007/s11426-018-9403-7},

number = {5},

pages = {571--582},

doi = {10.1007/s11426-018-9403-7}

}

MLA

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MLA Copy

Liu, Deshuai, et al. “Rare-earth metal catalysts for alkene hydrosilylation.” Science China Chemistry, vol. 62, no. 5, Feb. 2019, pp. 571-582. https://doi.org/10.1007/s11426-018-9403-7.

Publisher

Springer Nature

Journal

Science China Chemistry

scimago Q1

wos Q1

SJR

2.377

CiteScore

13.8

Impact factor

9.7

ISSN

16747291 (Print)

18691870 (Electronic)