Liquid-crystalline ordering in the solution of partially flexible macromolecules
Publication type: Journal Article
Publication date: 1982-06-01
scimago Q2
wos Q2
SJR: 0.669
CiteScore: 6.2
Impact factor: 3.1
ISSN: 03784371, 18732119
Condensed Matter Physics
Statistics and Probability
Abstract
The liquid-crystalline ordering in the solution of persistent chains which length, L, is comparable with the length of the effective Kuhn segment, l, is considered by means of a generalization of the Onsager method. The orientational entropy for this case is calculated using the method proposed by I.M. Lifshitz (for another problem) in 1968. It is shown that a slight flexibility of the persistent chain is sufficient for the complete change in the properties of the liquid-crystalline transition: for example, at L l ∼0.1 these properties are more similar to those which are characteristic for the semi-flexible limit ( L l ⪢1), than for the rigid rod limit ( L l ⪡1), although at such L l the geometric form of the macromolecule is much closer to the rodlike one.
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236
Total citations:
236
Citations from 2024:
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(2.54%)
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GOST
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Khokhlov A. R., Semenov A. N. Liquid-crystalline ordering in the solution of partially flexible macromolecules // Physica A: Statistical Mechanics and its Applications. 1982. Vol. 112. No. 3. pp. 605-614.
GOST all authors (up to 50)
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Khokhlov A. R., Semenov A. N. Liquid-crystalline ordering in the solution of partially flexible macromolecules // Physica A: Statistical Mechanics and its Applications. 1982. Vol. 112. No. 3. pp. 605-614.
Cite this
RIS
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TY - JOUR
DO - 10.1016/0378-4371(82)90199-6
UR - https://doi.org/10.1016/0378-4371(82)90199-6
TI - Liquid-crystalline ordering in the solution of partially flexible macromolecules
T2 - Physica A: Statistical Mechanics and its Applications
AU - Khokhlov, Alexei R.
AU - Semenov, A. N.
PY - 1982
DA - 1982/06/01
PB - Elsevier
SP - 605-614
IS - 3
VL - 112
SN - 0378-4371
SN - 1873-2119
ER -
Cite this
BibTex (up to 50 authors)
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@article{1982_Khokhlov,
author = {Alexei R. Khokhlov and A. N. Semenov},
title = {Liquid-crystalline ordering in the solution of partially flexible macromolecules},
journal = {Physica A: Statistical Mechanics and its Applications},
year = {1982},
volume = {112},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/0378-4371(82)90199-6},
number = {3},
pages = {605--614},
doi = {10.1016/0378-4371(82)90199-6}
}
Cite this
MLA
Copy
Khokhlov, Alexei R., and A. N. Semenov. “Liquid-crystalline ordering in the solution of partially flexible macromolecules.” Physica A: Statistical Mechanics and its Applications, vol. 112, no. 3, Jun. 1982, pp. 605-614. https://doi.org/10.1016/0378-4371(82)90199-6.
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