Coordination Chemistry Reviews, volume 438, pages 213799
Influence of phosphine (pincer) ligands on the transition metal hydrides reactivity
Publication type: Journal Article
Publication date: 2021-07-01
Journal:
Coordination Chemistry Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 20.6
ISSN: 00108545
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
• Dihydrogen bonding determines reactivity of metal hydrides. • Role of (di)hydrogen bonding and proton transfer in (de)hydrogenation processes. • Steric and electronic effects of phosphines on the reactivity. • Reactivity of palladium, nickel, iridium and rutenium pincer hydrides. Transition-metal hydride complexes are plenteous in organometallic chemistry. The reactivity of metal hydrides is determined by three possible pathways of M–H bond cleavage: homolytic cleavage yielding a hydrogen radical (H ), and heterolytic cleavage generating either a proton (H + ) or hydride (H − ). These steps, especially the proton and hydride transfer, are critical in a vast array of stoichiometric and catalytic transformations. Many late transition metal hydrides are supported by phosphine ligands, which allow tuning the electronic and steric properties at a metal center in a systematic and predictable way. In this non-exhaustive review we attempt to trace the influence of phosphines properties on the reactivity of transition metal hydrides in topical stoichiometric and catalytic processes highlighting the reactions’ mechanisms and the role of hydrogen bonding interactions in the intermediates of hydrogen transfer reactions.
Citations by journals
|
1
2
|
|
|
Chemistry - A European Journal
|
Chemistry - A European Journal
2 publications, 20%
|
|
Organometallics
|
Organometallics
2 publications, 20%
|
|
Energies
|
Energies
1 publication, 10%
|
|
Molecules
|
Molecules
1 publication, 10%
|
|
New Journal of Chemistry
|
New Journal of Chemistry
1 publication, 10%
|
|
Inorganics
|
Inorganics
1 publication, 10%
|
|
Green Chemistry Letters and Reviews
|
Green Chemistry Letters and Reviews
1 publication, 10%
|
|
Green Chemistry
|
Green Chemistry
1 publication, 10%
|
|
1
2
|
Citations by publishers
|
1
2
3
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
3 publications, 30%
|
|
Wiley
|
Wiley
2 publications, 20%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
2 publications, 20%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
2 publications, 20%
|
|
Taylor & Francis
|
Taylor & Francis
1 publication, 10%
|
|
1
2
3
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[1,2,6,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["10","20","60","10"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Chemistry - A European Journal","Organometallics","Energies","Molecules","New Journal of Chemistry","Inorganics","Green Chemistry Letters and Reviews","Green Chemistry"],"ids":[24708,1409,23828,1770,1404,4005,12833,1017],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp"],"datasets":[{"label":"","data":[2,2,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[20,20,10,10,10,10,10,10],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Multidisciplinary Digital Publishing Institute (MDPI)","Wiley","Royal Society of Chemistry (RSC)","American Chemical Society (ACS)","Taylor & Francis"],"ids":[202,11,123,40,18],"codes":[0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp"],"datasets":[{"label":"","data":[3,2,2,2,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[30,20,20,20,10],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
belkova N. V. et al. Influence of phosphine (pincer) ligands on the transition metal hydrides reactivity // Coordination Chemistry Reviews. 2021. Vol. 438. p. 213799.
GOST all authors (up to 50)
Copy
belkova N. V., Filippov O. A., Osipova E. Y., Safronov S. V., epstein L. M., shubina E. S. Influence of phosphine (pincer) ligands on the transition metal hydrides reactivity // Coordination Chemistry Reviews. 2021. Vol. 438. p. 213799.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.ccr.2021.213799
UR - https://doi.org/10.1016%2Fj.ccr.2021.213799
TI - Influence of phosphine (pincer) ligands on the transition metal hydrides reactivity
T2 - Coordination Chemistry Reviews
AU - belkova, Natalia V.
AU - Filippov, Oleg A.
AU - Osipova, Elena Y.
AU - Safronov, Sergey V
AU - epstein, Lina M.
AU - shubina, Elena S.
PY - 2021
DA - 2021/07/01 00:00:00
PB - Elsevier
SP - 213799
VL - 438
SN - 0010-8545
ER -
Cite this
BibTex
Copy
@article{2021_belkova,
author = {Natalia V. belkova and Oleg A. Filippov and Elena Y. Osipova and Sergey V Safronov and Lina M. epstein and Elena S. shubina},
title = {Influence of phosphine (pincer) ligands on the transition metal hydrides reactivity},
journal = {Coordination Chemistry Reviews},
year = {2021},
volume = {438},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016%2Fj.ccr.2021.213799},
pages = {213799},
doi = {10.1016/j.ccr.2021.213799}
}
Profiles