Coordination Chemistry Reviews, volume 458, pages 214421
Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
Gulyaeva Ekaterina S
1, 2
,
Valyaev Dmitry A
,
Osipova Elena S
,
Osipova Elena Y.
1
,
Buhaibeh Ruqaya
2
,
Canac Yves
2
,
Sortais Jean-Baptiste
2, 3
,
2
LCC-CNRS, Université de Toulouse, CNRS, UPS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France
|
3
Institut Universitaire de France, 1 rue Descartes, 75231 Paris cedex 05, France
|
Publication type: Journal Article
Publication date: 2022-05-01
Journal:
Coordination Chemistry Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 20.6
ISSN: 00108545
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
• Mn catalysts bearing bidentate ligands may be competitive with pincer systems. • Mn complexes without cooperative ligands can catalyze hydrogenation-type reactions. • Incorporation of N- or C-based donors in bidentate Mn catalysts is often beneficial. • Chemoselectivity in Mn-catalyzed hydrosilylation can be tuned by a tiny ligand choice. • Metal/ligand price balance makes Mn catalysts attractive for sustainable synthesis. Rapidly emerging application of organometallic manganese complexes incorporating less elaborated mono- and bidentate donor ligands in catalytic hydrogenation, transfer hydrogenation, hydrogen-borrowing and hydrosilylation processes is comprehensively reviewed. Special attention is devoted to the influence of the nature of donor moieties (P-, N- and C-donors) on the catalytic activity and/or selectivity, the comparison with structurally related polydentate systems and mechanistic aspects.
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Gulyaeva E. S. et al. Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes // Coordination Chemistry Reviews. 2022. Vol. 458. p. 214421.
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Gulyaeva E. S., Valyaev D. A., Osipova E. S., Osipova E. Y., Buhaibeh R., Canac Y., Sortais J., Valyaev D. A. Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes // Coordination Chemistry Reviews. 2022. Vol. 458. p. 214421.
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TY - JOUR
DO - 10.1016/j.ccr.2022.214421
UR - https://doi.org/10.1016%2Fj.ccr.2022.214421
TI - Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
T2 - Coordination Chemistry Reviews
AU - Gulyaeva, Ekaterina S
AU - Valyaev, Dmitry A
AU - Osipova, Elena S
AU - Osipova, Elena Y.
AU - Buhaibeh, Ruqaya
AU - Canac, Yves
AU - Sortais, Jean-Baptiste
AU - Valyaev, D. A.
PY - 2022
DA - 2022/05/01 00:00:00
PB - Elsevier
SP - 214421
VL - 458
SN - 0010-8545
ER -
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@article{2022_Gulyaeva,
author = {Ekaterina S Gulyaeva and Dmitry A Valyaev and Elena S Osipova and Elena Y. Osipova and Ruqaya Buhaibeh and Yves Canac and Jean-Baptiste Sortais and D. A. Valyaev},
title = {Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes},
journal = {Coordination Chemistry Reviews},
year = {2022},
volume = {458},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016%2Fj.ccr.2022.214421},
pages = {214421},
doi = {10.1016/j.ccr.2022.214421}
}