Coordination Chemistry Reviews, volume 471, pages 214744
Cyclopentadienyl complexes of group 9 metals in the total synthesis of natural products
Publication type: Journal Article
Publication date: 2022-11-01
Journal:
Coordination Chemistry Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 20.6
ISSN: 00108545
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
• A comprehensive review on the use of cyclopentadienyl complexes of Group 9 metals in the total synthesis of natural products is given. • This work shows the enhanced performances of these complexes in the sense of step and atom economy. • Key steps of the synthesis of more than 170 natural products (alkaloids, steroids, flavonoids, terpenoids, polyketides) are considered. • The conclusion and outlook are given for the future application. Organic transformations catalyzed by cyclopentadienyl complexes of Group 9 metals (cobalt, rhodium and iridium) are the key steps of the total synthesis of various natural products. These complexes efficiently catalyze [2 + 2 + 2] cycloaddition, asymmetric transfer hydrogenation, C–H activation reactions, including annulation, alkylation, olefination and amidation processes. The advantages and drawbacks of these transformations, as well as the reaction mechanisms, are discussed. The review is comprehensive and summarizes the information on the use of cyclopentadienyl complexes of Group 9 metals in the total synthesis of natural compounds, published in the literature up to 2021.
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Citations by publishers
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4
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Multidisciplinary Digital Publishing Institute (MDPI)
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4 publications, 22.22%
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Wiley
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4 publications, 22.22%
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American Chemical Society (ACS)
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kharitonov V. B. et al. Cyclopentadienyl complexes of group 9 metals in the total synthesis of natural products // Coordination Chemistry Reviews. 2022. Vol. 471. p. 214744.
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Kharitonov V. B., Muratov D. V., Loginov D. A. Cyclopentadienyl complexes of group 9 metals in the total synthesis of natural products // Coordination Chemistry Reviews. 2022. Vol. 471. p. 214744.
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TY - JOUR
DO - 10.1016/j.ccr.2022.214744
UR - https://doi.org/10.1016%2Fj.ccr.2022.214744
TI - Cyclopentadienyl complexes of group 9 metals in the total synthesis of natural products
T2 - Coordination Chemistry Reviews
AU - Kharitonov, Vladimir B.
AU - Muratov, Dmitry V.
AU - Loginov, Dmitry A.
PY - 2022
DA - 2022/11/01 00:00:00
PB - Elsevier
SP - 214744
VL - 471
SN - 0010-8545
ER -
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@article{2022_Kharitonov,
author = {Vladimir B. Kharitonov and Dmitry V. Muratov and Dmitry A. Loginov},
title = {Cyclopentadienyl complexes of group 9 metals in the total synthesis of natural products},
journal = {Coordination Chemistry Reviews},
year = {2022},
volume = {471},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016%2Fj.ccr.2022.214744},
pages = {214744},
doi = {10.1016/j.ccr.2022.214744}
}