Journal of Catalysis, volume 429, pages 115269
White-Light initiated Mn2(CO)10/HFIP-Catalyzed anti-Markovnikov hydrosilylation of alkenes
Goncharova Irina K
1, 2
,
Filatov Stepan A.
1, 3
,
Drozdov Anton P.
1, 2
,
Knyazev Pavel A.
5
,
Guda Alexander
4
,
Arzumanyan Ashot V
1, 2
Publication type: Journal Article
Publication date: 2024-01-01
Journal:
Journal of Catalysis
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 7.3
ISSN: 00219517, 10902694
Catalysis
Physical and Theoretical Chemistry
Abstract
This study presents a highly efficient and mild method for radical hydrosilylation of alkenes. The reaction proceeds under white-light, in the presence of Mn2(CO)10 pre-catalyst and HFIP as an additive, at r.t. and under air. Under white-light, [Mn]• is generated, which activates the Si–H-group to form Si• and trigger the autocatalytic process. HFIP acts as a unique activator which enables synthesis of the products with yields close to quantitative and with anti-Markovnikov selectivity. The method is applicable to terminal alkenes, including those with O-, N- and halogen-containing functional groups, styrene and allylbenzene derivatives, etc., as well as to a wide range of alkyl-, phenyl-, siloxy- and alkoxy-containing tertiary hydrosilanes. These conditions turned out to be most efficient for hydrosilylation of gaseous reagents such as ethylene and acetylene. In both cases the products showed quantitative yield at 1 atm and at r.t. The method is easily up-scalable in batch- and flow-modes.
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Goncharova I. K. et al. White-Light initiated Mn2(CO)10/HFIP-Catalyzed anti-Markovnikov hydrosilylation of alkenes // Journal of Catalysis. 2024. Vol. 429. p. 115269.
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Goncharova I. K., Filatov S. A., Drozdov A. P., Tereshchenko A. A., Knyazev P. A., Guda A., Beletskaya I. P., Arzumanyan A. V. White-Light initiated Mn2(CO)10/HFIP-Catalyzed anti-Markovnikov hydrosilylation of alkenes // Journal of Catalysis. 2024. Vol. 429. p. 115269.
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TY - JOUR
DO - 10.1016/j.jcat.2023.115269
UR - https://doi.org/10.1016%2Fj.jcat.2023.115269
TI - White-Light initiated Mn2(CO)10/HFIP-Catalyzed anti-Markovnikov hydrosilylation of alkenes
T2 - Journal of Catalysis
AU - Goncharova, Irina K
AU - Filatov, Stepan A.
AU - Drozdov, Anton P.
AU - Tereshchenko, Andrei Alexandrovich
AU - Knyazev, Pavel A.
AU - Guda, Alexander
AU - Beletskaya, Irina P.
AU - Arzumanyan, Ashot V
PY - 2024
DA - 2024/01/01 00:00:00
PB - Elsevier
SP - 115269
VL - 429
SN - 0021-9517
SN - 1090-2694
ER -
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@article{2024_Goncharova,
author = {Irina K Goncharova and Stepan A. Filatov and Anton P. Drozdov and Andrei Alexandrovich Tereshchenko and Pavel A. Knyazev and Alexander Guda and Irina P. Beletskaya and Ashot V Arzumanyan},
title = {White-Light initiated Mn2(CO)10/HFIP-Catalyzed anti-Markovnikov hydrosilylation of alkenes},
journal = {Journal of Catalysis},
year = {2024},
volume = {429},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.jcat.2023.115269},
pages = {115269},
doi = {10.1016/j.jcat.2023.115269}
}