A stereocontrolled total synthesis of methyl (±)-O-methylpodocarpate
Publication type: Journal Article
Publication date: 2003-06-09
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
A stereocontrolled total synthesis of methyl (±)-O-methyl podocarpate ( 4 ) has been successfully accomplished using the trans-fused diester 21 as a key intermediate. Intramolecular Michael reaction of the enone-diester 18 afforded the cis-fused keto-diester 19 in high yield which was stereoselectively converted into 21 via the enone 20 .
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GOST
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Roy A. et al. A stereocontrolled total synthesis of methyl (±)-O-methylpodocarpate // Tetrahedron Letters. 2003. Vol. 44. No. 26. pp. 4835-4837.
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Roy A., Paul T., Drew M. G. B., Mukherjee D. A stereocontrolled total synthesis of methyl (±)-O-methylpodocarpate // Tetrahedron Letters. 2003. Vol. 44. No. 26. pp. 4835-4837.
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RIS
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TY - JOUR
DO - 10.1016/s0040-4039(03)01124-9
UR - https://doi.org/10.1016/s0040-4039(03)01124-9
TI - A stereocontrolled total synthesis of methyl (±)-O-methylpodocarpate
T2 - Tetrahedron Letters
AU - Roy, Arnab
AU - Paul, Tapas
AU - Drew, Michael G. B.
AU - Mukherjee, Debabrata
PY - 2003
DA - 2003/06/09
PB - Elsevier
SP - 4835-4837
IS - 26
VL - 44
SN - 0040-4039
SN - 1873-3581
ER -
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BibTex (up to 50 authors)
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@article{2003_Roy,
author = {Arnab Roy and Tapas Paul and Michael G. B. Drew and Debabrata Mukherjee},
title = {A stereocontrolled total synthesis of methyl (±)-O-methylpodocarpate},
journal = {Tetrahedron Letters},
year = {2003},
volume = {44},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/s0040-4039(03)01124-9},
number = {26},
pages = {4835--4837},
doi = {10.1016/s0040-4039(03)01124-9}
}
Cite this
MLA
Copy
Roy, Arnab, et al. “A stereocontrolled total synthesis of methyl (±)-O-methylpodocarpate.” Tetrahedron Letters, vol. 44, no. 26, Jun. 2003, pp. 4835-4837. https://doi.org/10.1016/s0040-4039(03)01124-9.