Intermolecular hydrogen bonds with d-electrons of transition metal atoms. H-complexes with metallocenes of the iron subgroup
Publication type: Journal Article
Publication date: 1993-12-01
scimago Q2
wos Q2
SJR: 0.628
CiteScore: 8.0
Impact factor: 4.7
ISSN: 00222860, 18728014
Organic Chemistry
Inorganic Chemistry
Spectroscopy
Analytical Chemistry
Abstract
Hydrogen bonding of phenol (phenol- d ) and p -substituted phenols (R = F, NO 2 ) with d-electrons of the metal atom in ruthenocene and osmocene was examined. Two types of the ν(bonded OH) bands, ν(OH⋯π) and ν(OH⋯M), were observed in the IR spectra. Hydrogen bonding of the OH⋯M type was shown to have the usual spectral characteristics: correlation with basicity, common temperature dependence and isotopic ratio. The peculiarities of the hydrogen-bonding ability of d-electrons in comparison with those of sp-electrons are discussed.
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Total citations:
27
Citations from 2025:
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Shubina E. S. et al. Intermolecular hydrogen bonds with d-electrons of transition metal atoms. H-complexes with metallocenes of the iron subgroup // Journal of Molecular Structure. 1993. Vol. 301. pp. 1-5.
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Shubina E. S., Krylov A., Kreindlin A. Z., Rybinskaya M. I., Epstein L. M. Intermolecular hydrogen bonds with d-electrons of transition metal atoms. H-complexes with metallocenes of the iron subgroup // Journal of Molecular Structure. 1993. Vol. 301. pp. 1-5.
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TY - JOUR
DO - 10.1016/0022-2860(93)80225-K
UR - https://doi.org/10.1016/0022-2860(93)80225-K
TI - Intermolecular hydrogen bonds with d-electrons of transition metal atoms. H-complexes with metallocenes of the iron subgroup
T2 - Journal of Molecular Structure
AU - Shubina, Elena S.
AU - Krylov, A.N.
AU - Kreindlin, A Z
AU - Rybinskaya, M. I.
AU - Epstein, L M
PY - 1993
DA - 1993/12/01
PB - Elsevier
SP - 1-5
VL - 301
SN - 0022-2860
SN - 1872-8014
ER -
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@article{1993_Shubina,
author = {Elena S. Shubina and A.N. Krylov and A Z Kreindlin and M. I. Rybinskaya and L M Epstein},
title = {Intermolecular hydrogen bonds with d-electrons of transition metal atoms. H-complexes with metallocenes of the iron subgroup},
journal = {Journal of Molecular Structure},
year = {1993},
volume = {301},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/0022-2860(93)80225-K},
pages = {1--5},
doi = {10.1016/0022-2860(93)80225-K}
}
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