Antiferromagnetic complexes with the metalmetal bond
Igor L. Eremenko
1
,
S.E. Nefedov
1
,
A. A. Pasynskii
1
,
B Orazsakhatov
1
,
O.G Ellert
1
,
Yu. T. Struchkov
2
,
A. I. Yanovsky
2
,
D V Zagorevsky
2
Publication type: Journal Article
Publication date: 1989-06-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Interaction of (MeC 5 H 4 ) 2 Cr with oxygen or selenium results in formation of 60-electron clusters (MeC 5 H 4 ) 4 Cr 4 (μ 3 -O) 4 (I) and (MeC 5 H 4 ) 4 Cr 4 (μ 3 -Se) 4 (III). Their structures were determined by X-ray diffraction study (I: space group I 4, a = b = 13.0857(7), c = 7.0538(4) A, V = 1207.9 A 3 , Z = 2, R 1 = 0.058, R w = 0.066; III: space group Pbca, a = 18.456(2), b = 17.164(1), c = 16.227(2) A, V = 5140.4 A 3 , Z = 8, R 1 = 0.054, R w = 0.047). In contrast to the relatively symmetrical structure of sulfide (MeC 5 H 4 ) 4 Cr 4 (μ 3 -S) 4 (II) (CrCr 2 × 2.848 and 4 × 2.822 A) and selenide III, in I a pronounced tetrahedral distortion of the metal core is observed (CrCr 2 × 2.896(3) and 4 × 2.759(3) A). All the CrCr bonds in III are elongated, compared with those in II (up to ∼ 3.00–3.04 A). The oxide cluster I is antiferromagnetic whereas the analogous sulfide and selenide clusters are diamagnetic.
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GOST
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Eremenko I. L. et al. Antiferromagnetic complexes with the metalmetal bond // Journal of Organometallic Chemistry. 1989. Vol. 368. No. 2. pp. 185-192.
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Eremenko I. L., Nefedov S., Pasynskii A. A., Orazsakhatov B., Ellert O., Struchkov Y. T., Yanovsky A. I., Zagorevsky D. V. Antiferromagnetic complexes with the metalmetal bond // Journal of Organometallic Chemistry. 1989. Vol. 368. No. 2. pp. 185-192.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/0022-328X(89)85313-6
UR - https://doi.org/10.1016/0022-328X(89)85313-6
TI - Antiferromagnetic complexes with the metalmetal bond
T2 - Journal of Organometallic Chemistry
AU - Eremenko, Igor L.
AU - Nefedov, S.E.
AU - Pasynskii, A. A.
AU - Orazsakhatov, B
AU - Ellert, O.G
AU - Struchkov, Yu. T.
AU - Yanovsky, A. I.
AU - Zagorevsky, D V
PY - 1989
DA - 1989/06/01
PB - Elsevier
SP - 185-192
IS - 2
VL - 368
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
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@article{1989_Eremenko,
author = {Igor L. Eremenko and S.E. Nefedov and A. A. Pasynskii and B Orazsakhatov and O.G Ellert and Yu. T. Struchkov and A. I. Yanovsky and D V Zagorevsky},
title = {Antiferromagnetic complexes with the metalmetal bond},
journal = {Journal of Organometallic Chemistry},
year = {1989},
volume = {368},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/0022-328X(89)85313-6},
number = {2},
pages = {185--192},
doi = {10.1016/0022-328X(89)85313-6}
}
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MLA
Copy
Eremenko, Igor L., et al. “Antiferromagnetic complexes with the metalmetal bond.” Journal of Organometallic Chemistry, vol. 368, no. 2, Jun. 1989, pp. 185-192. https://doi.org/10.1016/0022-328X(89)85313-6.
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