Crown compounds for anions. A polymeric complex of cyclic trimeric perfluoro-o-phenylenemercury with thiocyanate anion containing an infinite helical chain of alternating molecules of mercury-containing macrocycle and SCN− ions
I.A Tikhonova
1
,
A. I. Yanovsky
1
,
F.M. Dolgushin
1
,
Yu. T. Struchkov
1
,
A N Gavrilova
1
,
L N Saitkulova
1
,
L M Epstein
1
,
G.G Furin
1
,
Elena S. Shubina
1
,
Publication type: Journal Article
Publication date: 1996-02-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
It has been shown by IR spectroscopy that cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)3 is capable of binding thiocyanate anions in acetone solution, forming complexes whose composition is dependent on the ratio of reagents. In the interaction of (o-C6F4Hg)3 with an equimolar amount of [nBu4N]+ SCN− in ethanol the complex formulated as [(o- C 6 F 4 Hg ) 3 ( SCN )] − [ n Bu 4 N ] + has been isolated. An X-ray diffraction study of the complex has revealed that in the solid state it is polymeric and contains an infinite helical chain of alternating (o-C6F4Hg)3 molecules and thiocyanate anions. Every SCN− ion in the complex is bonded to the mercury atoms of two neighbouring molecules of the macrocycle through the sulphur atom and forms with each of these molecules two relatively short Hg … S bonds and one considerably longer Hg … S bond.
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Citations from 2024:
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GOST
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Tikhonova I. et al. Crown compounds for anions. A polymeric complex of cyclic trimeric perfluoro-o-phenylenemercury with thiocyanate anion containing an infinite helical chain of alternating molecules of mercury-containing macrocycle and SCN− ions // Journal of Organometallic Chemistry. 1996. Vol. 508. No. 1-2. pp. 271-273.
GOST all authors (up to 50)
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Tikhonova I., Yanovsky A. I., Dolgushin F., Struchkov Y. T., Gavrilova A. N., Saitkulova L. N., Epstein L. M., Furin G., Shubina E. S., Shur V. Y. Crown compounds for anions. A polymeric complex of cyclic trimeric perfluoro-o-phenylenemercury with thiocyanate anion containing an infinite helical chain of alternating molecules of mercury-containing macrocycle and SCN− ions // Journal of Organometallic Chemistry. 1996. Vol. 508. No. 1-2. pp. 271-273.
Cite this
RIS
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TY - JOUR
DO - 10.1016/0022-328X(95)05965-R
UR - https://doi.org/10.1016/0022-328X(95)05965-R
TI - Crown compounds for anions. A polymeric complex of cyclic trimeric perfluoro-o-phenylenemercury with thiocyanate anion containing an infinite helical chain of alternating molecules of mercury-containing macrocycle and SCN− ions
T2 - Journal of Organometallic Chemistry
AU - Tikhonova, I.A
AU - Yanovsky, A. I.
AU - Dolgushin, F.M.
AU - Struchkov, Yu. T.
AU - Gavrilova, A N
AU - Saitkulova, L N
AU - Epstein, L M
AU - Furin, G.G
AU - Shubina, Elena S.
AU - Shur, Vladimir Ya.
PY - 1996
DA - 1996/02/01
PB - Elsevier
SP - 271-273
IS - 1-2
VL - 508
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1996_Tikhonova,
author = {I.A Tikhonova and A. I. Yanovsky and F.M. Dolgushin and Yu. T. Struchkov and A N Gavrilova and L N Saitkulova and L M Epstein and G.G Furin and Elena S. Shubina and Vladimir Ya. Shur},
title = {Crown compounds for anions. A polymeric complex of cyclic trimeric perfluoro-o-phenylenemercury with thiocyanate anion containing an infinite helical chain of alternating molecules of mercury-containing macrocycle and SCN− ions},
journal = {Journal of Organometallic Chemistry},
year = {1996},
volume = {508},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/0022-328X(95)05965-R},
number = {1-2},
pages = {271--273},
doi = {10.1016/0022-328X(95)05965-R}
}
Cite this
MLA
Copy
Tikhonova, I.A, et al. “Crown compounds for anions. A polymeric complex of cyclic trimeric perfluoro-o-phenylenemercury with thiocyanate anion containing an infinite helical chain of alternating molecules of mercury-containing macrocycle and SCN− ions.” Journal of Organometallic Chemistry, vol. 508, no. 1-2, Feb. 1996, pp. 271-273. https://doi.org/10.1016/0022-328X(95)05965-R.
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