Crystal structure of triclinic CeP5O14: A new type of ultraphosphate
1
Laboratoire de Physico-Chimie Minérale, Ecole Normale Supérieure 43, Rue de la liberté le Bardo, Tunis, France
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2
Laboratoire de Cristallographie, CNRS Laboratoire Associéà l'USMG, 166X Centre de Tri. 38042 Grenoble Cedex, France
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Publication type: Journal Article
Publication date: 1984-03-01
scimago Q2
wos Q1
SJR: 0.629
CiteScore: 6.8
Impact factor: 3.5
ISSN: 00224596, 1095726X
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
The new form of cerium(III) ultraphosphate, CeP 5 O 14 described here is triclinic with a = 9.227(5), b = 8.890(5), c = 7.219(4)Å, α = 110.12(5)°, β = 102.68(5)°, γ = 82.13(5)°. Space group is P 1. Z = 2. D x = 3.186 mg/m 3 . Crystal structure of this salt has been solved by using 4587 independent reflections with a final R value 0.029. The atomic arrangement can be described as [P 10 O 28 ] sheets spreading in (110) planes. The internal structure of these sheets is mainly a linkage of (P 12 O 36 ) rings in which 40% of the phosphorus atoms are branching phosphorus.
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RZAIGUI M. et al. Crystal structure of triclinic CeP5O14: A new type of ultraphosphate // Journal of Solid State Chemistry. 1984. Vol. 52. No. 1. pp. 61-65.
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RZAIGUI M., Ariguib N., Averbuch-Pouchot M., Durif A. Crystal structure of triclinic CeP5O14: A new type of ultraphosphate // Journal of Solid State Chemistry. 1984. Vol. 52. No. 1. pp. 61-65.
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TY - JOUR
DO - 10.1016/0022-4596(84)90198-1
UR - https://doi.org/10.1016/0022-4596(84)90198-1
TI - Crystal structure of triclinic CeP5O14: A new type of ultraphosphate
T2 - Journal of Solid State Chemistry
AU - RZAIGUI, M.
AU - Ariguib, N.Kbir
AU - Averbuch-Pouchot, M.-T.
AU - Durif, A.
PY - 1984
DA - 1984/03/01
PB - Elsevier
SP - 61-65
IS - 1
VL - 52
SN - 0022-4596
SN - 1095-726X
ER -
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@article{1984_RZAIGUI,
author = {M. RZAIGUI and N.Kbir Ariguib and M.-T. Averbuch-Pouchot and A. Durif},
title = {Crystal structure of triclinic CeP5O14: A new type of ultraphosphate},
journal = {Journal of Solid State Chemistry},
year = {1984},
volume = {52},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/0022-4596(84)90198-1},
number = {1},
pages = {61--65},
doi = {10.1016/0022-4596(84)90198-1}
}
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MLA
Copy
RZAIGUI, M., et al. “Crystal structure of triclinic CeP5O14: A new type of ultraphosphate.” Journal of Solid State Chemistry, vol. 52, no. 1, Mar. 1984, pp. 61-65. https://doi.org/10.1016/0022-4596(84)90198-1.