Mechanistic study of palladium catalyzed S-S and Se-Se bonds addition to alkynes
Publication type: Journal Article
Publication date: 2003-12-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The mechanistic study of palladium catalyzed S � /S and Se � /Se bonds addition to alkynes revealed the involvement of dinuclear transition metal complexes in the catalytic cycle. Coordination of alkyne to dinuclear transition metal complex was found to be the rate determining step of the reaction. An unusual phosphine ligand effect increasing the yield of addition reaction was found in the studied system. A new synthetic procedure was developed to perform the catalytic reaction using easily available Pd(II) complex. The scope of the reaction and the reactivity of S � /S and Se � /Se bonds toward alkynes were investigated. The X-ray structure of the product of S � /S bond addition reaction showed favorable geometry for the possible application as a chelate ligand. # 2003 Elsevier B.V. All rights reserved.
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GOST
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Kabeshov M. A. et al. Mechanistic study of palladium catalyzed S-S and Se-Se bonds addition to alkynes // Journal of Organometallic Chemistry. 2003. Vol. 687. No. 2. pp. 451-461.
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Ananikov V. P., Kabeshov M. A., Aleksandrov G. G., Beletskaya I. P., Eremenko I. L. Mechanistic study of palladium catalyzed S-S and Se-Se bonds addition to alkynes // Journal of Organometallic Chemistry. 2003. Vol. 687. No. 2. pp. 451-461.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0022-328X(03)00795-2
UR - https://doi.org/10.1016/S0022-328X(03)00795-2
TI - Mechanistic study of palladium catalyzed S-S and Se-Se bonds addition to alkynes
T2 - Journal of Organometallic Chemistry
AU - Ananikov, Valentine P.
AU - Kabeshov, Michael A
AU - Aleksandrov, Grigory G.
AU - Beletskaya, Irina P.
AU - Eremenko, Igor L.
PY - 2003
DA - 2003/12/01
PB - Elsevier
SP - 451-461
IS - 2
VL - 687
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
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@article{2003_Kabeshov,
author = {Valentine P. Ananikov and Michael A Kabeshov and Grigory G. Aleksandrov and Irina P. Beletskaya and Igor L. Eremenko},
title = {Mechanistic study of palladium catalyzed S-S and Se-Se bonds addition to alkynes},
journal = {Journal of Organometallic Chemistry},
year = {2003},
volume = {687},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/S0022-328X(03)00795-2},
number = {2},
pages = {451--461},
doi = {10.1016/S0022-328X(03)00795-2}
}
Cite this
MLA
Copy
Kabeshov, Michael A., et al. “Mechanistic study of palladium catalyzed S-S and Se-Se bonds addition to alkynes.” Journal of Organometallic Chemistry, vol. 687, no. 2, Dec. 2003, pp. 451-461. https://doi.org/10.1016/S0022-328X(03)00795-2.